Journal of Advanced Ceramics•2026•DOI: 10.26599/JAC.2026.9221348
Advanced temperature-sensitive materials are critical for hypersonic propulsion and next-generation energy systems, yet long-term stability above 1000 °C remains a formidable barrier. Conventional transition-metal spinel oxides (e.g., Ni–Mn–Co–O) suffer phase decomposition and cation migration above 300 °C, causing exponential resistance drift. This work develops a Mo-regulated high-entropy ferroelastic niobate strategy for ultrawide-temperature negative-temperature-coefficient (NTC) thermosensitive ceramics. Density functional theory calculations reveal that A-site high-entropy facilitates Mo doping in (Ca0.2La0.2Ce0.2Eu0.2Gd0.2)NbO4. Mo doping broadens local atomic configurations, modulates ferroelastic domain structures, and increases atomic-scale displacement disorder, redistributing Hall transport contributions and reducing grain/grain-boundary transport barrier mismatch. The optimized HEN-0.2Mo ceramic exhibits highly linear Arrhenius behavior (R² = 0.99907) from −50 to 1250 °C with a B-value fluctuation of only 4.44%. High-temperature impedance analysis confirms closely matched grain and grain-boundary activation energies (Eg = 1.209 eV, Egb = 1.218 eV; ΔEa ≈ 0.009 eV). During 1250 °C aging, postdensification and strain redistribution yield a stabilized-stage resistance drift of only 1.09% after 1000 h. These findings demonstrate that entropy-stabilized defect engineering decouples sensitivity from degradation in functional ceramics under thermal stress.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2026•DOI: 10.1088/1674-4926/26020026
Ferroelectric domain walls are conventionally regarded as two-dimensional (2D) interfacial objects that separate regions of different polarization within a crystal. This picture has guided decades of research into polarization switching, domain evolution, and ferroic functionality. In most ferroelectrics, electrostatic considerations strongly favor head-to-tail (H–T) polarization configurations, which minimize bound charge and reduce electrostatic energy. By contrast, charged domain walls (CDWs) carry positive or negative bound polarization charge and form where polarization vectors arrange head-to-head (H–H) or tail-to-tail (T–T), generally considered energetically unfavorable. When such charged walls do occur, they are typically stabilized only as extended 2D structures through a combination of electronic screening, defect accumulation, and lattice relaxation. Despite these energetic constraints, CDWs have attracted growing interest over the past decade because of their emergent functional properties, including enhanced electrical conductivity, strong electromechanical coupling, and reconfigurable electronic behavior localized at charged walls, motivating the broader concept of domain-wall nanoelectronics. Nevertheless, ferroelectric domain walls have almost universally been treated as quasi-2D objects. Further reduction of their dimensionality has long been assumed to be impractical, particularly for charged walls, because confining bound polarization charge to lower dimensions would dramatically increase electrostatic energy. Against this backdrop, Zhong et al. reported the direct observation of one-dimensional (1D) CDWs confined within individual polar layers of ferroelectric ZrO2 (Science (2026)). Using atomic-resolution electron microscopy combined with in situ electric-field manipulation, they demonstrated that both H–H and T–T CDWs can exist as atomic-scale line defects rather than extended 2D interfaces, with their bound polarization charge stabilized through a self-balancing oxygen compensation mechanism. The discovery represents an extreme limit of ferroelectric domain-wall confinement and introduces a fundamentally new class of polar topological objects that occupy an intermediate conceptual regime between conventional domain walls and line defects.
China Foundry•2026•DOI: 10.1007/s41230-026-5163-9
In laser powder bed fusion (LPBF) additive manufacturing, surface depressions caused by melt pool instability can induce defects throughout the layer-by-layer printing process. To address the limited understanding of interlayer defect transmission mechanisms, synchrotron X-ray in situ imaging was used to systematically investigate the dynamic evolution of surface depressions during multi-pass printing by adjusting interlayer process parameters. Experimental results show that insufficient energy input in the first layer leads to balling and fracture of melt tracks. When the energy input in the second layer is increased, local overheating at the gap between melt tracks from the previous layer causes surface depressions. Reducing the energy input in the third layer hinders melt backflow, enlarging the depression region. Further lowering the energy input in the final layer leads to the formation of internal unfused defects. This study reveals the dynamic correlation between surface depressions and interlayer defect evolution, offering critical experimental evidence and theoretical guidance for closed-loop interlayer process control in laser additive manufacturing.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01997-6
Single-atom catalysts (SACs) have demonstrated excellent performance in heterogeneous catalytic reactions owing to their maximized atomic efficiency, distinctive geometric, and electronic configurations. However, the efficacy of SACs remains limited for certain reactions requiring simultaneous activation of multiple reactants over metallic active sites. Herein, we report an atomically dispersed Pt1Ru1 dual-atom pair site anchored on nanodiamond@graphene (ND@G) for CO oxidation. The Pt1Ru1 dual-atom catalyst shows an exceptional turnover frequency (TOF) of 17.6 × 10−2 s−1 at significantly lower temperature (30 °C), achieving a tenfold increase in TOF compared to single-atom Pt1/ND@G catalyst (1.5 × 10−2 s−1) and surpassing to previously reported Pt-based catalysts under similar conditions. Moreover, the catalyst demonstrates excellent stability, maintaining its activity for 40 h at 80 °C without significant deactivation. The superior catalytic performance of Pt-Ru dual-atom catalysts is attributed to the synergistic effect between Pt and Ru atoms with enhanced metallicity for improving simultaneous adsorption and activation of CO and O2, and the tuning of conventional competitive reactant adsorption into a non-competitive pathway over dual-atom pair sites. The present work manifests the advantages of dual-atom pair sites in heterogeneous catalysis and paves the way for precise design of catalysts at the atomic scale.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01992-x
Conversion-type electrode materials hold significant promise for potassium-ion batteries (PIBs) due to their high theoretical capacities, yet their practical deployment is hindered by sluggish kinetics and irreversible structural degradation. To overcome these limitations, we propose a rationally engineered nanoreactor architecture that stabilizes defect-rich MoS2 via interlayer incorporation of a carbon monolayer, followed by encapsulation within a nitrogen-doped carbon shell, forming a MoSSe@NC heterostructure. This tailored structure synergistically accelerates both K+ diffusion kinetics and electron transfer, enabling unprecedented rate performance (107 mAh g−1 at 10 A g−1) and ultralong cyclability (86.5% capacity retention after 1200 cycles at 3 A g−1). Mechanistic insights reveal a distinctive “adsorption-conversion” pathway, where sulfur vacancies on exposed S–Mo–S basal planes act as preferential K+ adsorption sites, effectively suppressing parasitic phase transitions during intercalation. In situ X-ray diffraction and transmission electron microscopy corroborate the structural reversibility of the conversion reaction, with the carbon matrix dynamically accommodating strain while preserving electrode integrity. This work not only advances the understanding of defect-driven interfacial chemistry in conversion-type materials but also provides a versatile strategy for designing high-performance anodes in next-generation PIBs through heterostructure engineering.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-02009-3
Stretchable electronics have been recognized as intriguing next-generation electronics that possess huge market value, and stretchable electronic conductors (SECs) are essential for stretchable electronics, which not only can serve as critical functional components but also are the indispensable electronic connections bridging various electronic components within stretchable electronic systems. Herein, we offer a comprehensive review of recent progress in SECs including the material categories, structure designs, fabrication techniques, and applications. The characteristics, performance enhancement strategies, and application requirements are emphasized. Based on the recent advances, the existing challenges and future prospects are outlined and discussed.
Journal of Central South University•2026•DOI: 10.1007/s11771-026-6237-y
Intergrown ferromanganese ore resources are typical strategic mineral resources with huge reserves and abundant hematite, pyrolusite, and other valuable minerals, which is of great significance for its development and utilization. This paper adopts a combination of phase transformation and magnetic separation to explore the phase transformation mechanism of Fe minerals and Mn minerals during the roasting process. The analysis of the properties of the raw ore shows that the Fe-containing and Mn-containing minerals of the intergrown ferromanganese ore are hematite and pyrolusite, respectively. The optimal conditions for controlling the mineral phase were obtained, including roasting temperature of 600 ℃ for 30 min, and a grinding fineness of <0.074 mm accounting for 50%. Meanwhile, a Fe grade of 61.05% with a recovery of 80.77%, and a Mn grade of 61.60% with a recovery of 87.81% were acquired. The precise mineral phase transformation (MPT) could be realized via adjusting the roasting conditions. Hematite is transformed into magnetite, while pyrolusite is transformed into manganosite, and then they were effectively separated and concentrated via magnetic separation.
Journal of Central South University•2026•DOI: 10.1007/s11771-025-6070-8
Graphite has the potential to mediate the reduction process of Cr(VI) by oxalic acid (OA), but a reasonable modification is required to enhance the mediation of electron transfer. In this study, biosynthetic Schwertmannite (Sch) modified graphite (Sch@G) was pyrolyzed at 700℃ for Cr(VI) remediation. Biosynthetic Sch particles were successfully loaded on the graphite, providing high specific surface area and abundant O-containing functional groups. The removal efficiency of Cr(VI) reached 90.42% within 60 min, facilitated by the synergistic between 1 g/L Sch@G and 1 mmol/L OA. Additionally, the comparative experiments exhibited a significant capacity of Sch@G in a wide pH range (pH 2−10), the removal efficiency was 97.9% within 60 min even at pH 10. Furthermore, the catalyst presented superior environmental adaptability in solutions containing various types of anions (Cl−, SO4^2−, NO3−, H2PO4−). Mechanism analysis revealed that the catalyst greatly promotes the transfer of electrons from OA to Cr-contaminants, along with the release of low-valent Fe from Sch, enabling efficient electrons transfer to the Cr-contaminant. Meanwhile, the addition of OA could complex OA-Cr(VI) compound, lowering the activity of Cr(VI) and facilitating the subsequent Cr(VI) removal. Generally, the synergistic effect of the catalyst and OA can form an efficient system that enables rapid and effective remediation of Cr(VI) contamination across a wide pH range. Thus, the catalyst presents as a promising graphite-based biomaterial for the rapid and effective remediation of Cr(VI) contaminants from wastewater.
Journal of Central South University•2026•DOI: 10.1007/s11771-025-6108-y
With increasing mining depth in metal mines, the stability of roadway support structures is significantly affected by the complex surrounding rock. This study performs biaxial compression and bolt pull-out experiments on anchorage body specimens with different structural plane dip angles to explore failure mechanisms of anchorage structures and evolutionary law of bolt anchorage force. Results show the dip angle notably impacts the bearing capacity and failure modes of anchorage specimens. Their peak stress exhibits a V-shaped trend: decreasing from 54.80 MPa to 19.65 MPa as dip angles increase from 0° to 45°, with failure mode transitioning from tensile to shear; at 60°, it becomes a tensile-dominated mixed mode. Bolt anchoring significantly enhances bearing capacity (most remarkably by 153.22% at 45°) and changes failure from brittle to ductile. Pull-out tests reveal two failure modes: slip at the bolt-rock interface and bolt fracture. At 45°, bolt fracture occurs under a 14.55 kN peak pull-out load, matching the bolt's yield strength. This failure mechanism involves two key factors: structural plane sliding that shears the bolt, and mechanical interlocking that restricts pull-out, substantially increasing anchorage force. These findings provide insights for stability assessment and support design of roadway structures in complex geological environments.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01753-w
Joint health is critical for musculoskeletal (MSK) conditions that are affecting approximately one-third of the global population. Monitoring of joint torque can offer an important pathway for the evaluation of joint health and guided intervention. However, there is no technology that can provide the precision, effectiveness, low-resource setting, and long-term wearability to simultaneously achieve both rapid and accurate joint torque measurement to enable risk assessment of joint injury and long-term monitoring of joint rehabilitation in wider environments. Herein, we propose a piezoelectric boron nitride nanotubes (BNNTs)-based, AI-enabled wearable device for regular monitoring of joint torque. We first adopted an iterative inverse design to fabricate the wearable materials with a Poisson’s ratio precisely matched to knee biomechanics. A highly sensitive piezoelectric film was constructed based on BNNTs and polydimethylsiloxane and applied to precisely capture the knee motion, while concurrently realizing self-sufficient energy harvesting. With the help of a lightweight on-device artificial neural network, the proposed wearable device was capable of accurately extracting targeted signals from the complex piezoelectric outputs and then effectively mapping these signals to their corresponding physical characteristics, including torque, angle, and loading. A real-time platform was constructed to demonstrate the capability of fine real-time torque estimation. This work offers a relatively low-cost wearable solution for effective, regular joint torque monitoring that can be made accessible to diverse populations in countries and regions with heterogeneous development levels, potentially producing wide-reaching global implications for joint health, MSK conditions, ageing, rehabilitation, personal health, and beyond.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01703-6
Photocatalytic seawater splitting is an attractive way for producing green hydrogen. Significant progresses have been made recently in catalytic efficiencies, but the activity of catalysts can only maintain stable for about 10 h. Here, we develop a vacancy-engineered Ag3PO4/CdS porous microreactor chip photocatalyst, operating in seawater with a performance stability exceeding 300 h. This is achieved by the establishment of both catalytic selectivity for impurity ions and tailored interactions between vacancies and sulfur species. Efficient transport of carriers with strong redox ability is ensured by forming a heterojunction within a space charge region, where the visualization of potential distribution confirms the key design concept of our chip. Moreover, the separation of oxidation and reduction reactions in space inhibits the reverse recombination, making the chip capable of working at atmospheric pressure. Consequently, in the presence of Pt co-catalysts, a high solar-to-hydrogen efficiency of 0.81% can be achieved in the whole durability test. When using a fully solar-driven 256 cm2 hydrogen production prototype, a H2 evolution rate of 68.01 mmol h−1 m−2 can be achieved under outdoor insolation. Our findings provide a novel approach to achieve high selectivity, and demonstrate an efficient and scalable prototype suitable for practical solar H2 production.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01636-6
The coupling of fast redox kinetics, high-energy density, and prolonged lifespan is a permanent aspiration for aqueous rechargeable zinc batteries, but which has been severely hampered by a narrow voltage range and suboptimal compatibility between the electrolytes and electrodes. Here, we unprecedentedly introduced an electric ambipolar effect for synergistic manipulation on Zn2+ ternary-hydrated eutectic electrolyte (ZTE) enabling high-performance Zn-Br2 batteries. The electric ambipolar effect motivates strong dipole interactions among hydrated perchlorates and bipolar ligands of L-carnitine (L-CN) and sulfamide, which reorganized primary cations solvation sheath in a manner of forming Zn[(L-CN)(SA)(H2O)4]2+ configuration and dynamically restricting desolvated H2O molecules, thus ensuring a broadened electrochemical window of 2.9 V coupled with high ionic conductivity. Noticeably, L-CN affords an electrostatic shielding effect and an in situ construction of organic–inorganic interphase, endowing oriented Zn anode plating/stripping reversibly for over 2400 h. Therefore, with the synergy of electro/nucleophilicity and exceptional compatibility, the ZTE electrolyte dynamically boosts the conversion redox of Zn-Br2 batteries in terms of high specific capacity and stable cycling performance. These findings open a window for designing electrolytes with synergetic chemical stability and compatibility toward advanced zinc-ion batteries.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01667-7
The electrochemical performance of all-solid-state lithium batteries (ASSLBs) can be prominently enhanced by minimizing the detrimental degradation of solid electrolytes through their undesirable side reactions with the conductive carbon additives (CCAs) inside the composite cathodes. Herein, the well-defined Mo3Ni3N nanosheets embedded onto the N-doped porous carbons (NPCs) substrate are successfully synthesized (Mo-Ni@NPCs) as CCAs inside LiCoO2 for Li6PSC5Cl (LPSCl)-based ASSLBs. This nano-composite not only makes it difficult for hydroxide groups (–OH) to survive on the surface but also allows the in situ surface reconstruction to generate the ultra-stable MoS2-Mo3Ni3N heterostructures after the initial cycling stage. These can effectively prevent the occurrence of OH-induced LPSC decomposition reaction from producing harmful insulating sulfates, as well as simultaneously constructing the highly-efficient electrons/ions dual-migration pathways at the cathode interfaces to facilitate the improvement of both electrons and Li+ ions conductivities in ASSLBs. With this approach, fine-tuned Mo-Ni@NPCs can deliver extremely outstanding performance, including an ultra-high first discharge-specific capacity of 148.61 mAh g−1 (0.1C), a high Coulombic efficiency (94.01%), and a capacity retention rate after 1000 cycles still attain as high as 90.62%. This work provides a brand-new approach of “conversion-protection” strategy to overcome the drawbacks of composite cathodes interfaces instability and further promotes the commercialization of ASSLBs.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01662-y
The use of microneedles (MNs) has been established as an effective transdermal drug delivery strategy that has been extensively deployed for treating various diseases, including skin diseases. MNs can surpass the constraints of conventional drug delivery methods by their superior safety and efficacy through precise targeting, while simultaneously enabling painless delivery. Currently, MNs are increasingly used as carriers for drug delivery, with the loading of insoluble drugs to improve their treatment efficiency or combining with bioactive substances for the construction of an efficient drug delivery system to maximize the effects of bioactive substances. The methods used for preparation MNs are diverse, enabling them to meet the requirements of most applications. The emergence of MNs has addressed the shortcomings associated with insoluble drugs, expanded the applications of bioactive substances, and improved their use in clinical practice. This review summarizes current information on the application of MNs in a variety of skin diseases, such as psoriasis, vitiligo, alopecia, hypertrophic scarring, atopic dermatitis, melanoma, acne, and skin infections. The current clinical applications and future opportunities for MNs in the treatment of skin diseases are also discussed. Despite substantial progress in the clinical application of MNs as delivery vectors, issues such as low drug loading and poor mechanical strength during MNs preparation remain the main challenges. Therefore, clinical implementation of MNs-based therapies remains limited, highlighting key opportunities for future research.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01639-3
Carbon-based perovskite solar cells (C-PSCs) exhibit notable stability and durability. However, the power conversion efficiency (PCE) is significantly hindered by energy level mismatches, which result in interfacial charge transport barriers at the electrode-related interfaces. Herein, we report a back electrode that utilizes atomically dispersed metallic cobalt (Co) in carbon nanosheets (Co1/CN) to adjust the interfacial energy levels. The electrons in the d-orbitals of Co atoms disrupt the electronic symmetry of the carbon nanosheets (CN), inducing a redistribution of the electronic density of states that leads to a downward shift in the Fermi level and a significantly reduced interfacial energy barrier. As a result, the C-PSCs using Co1/CN as back electrodes achieve a notable PCE of 22.61% with exceptional long-term stability, maintaining 94.4% of their initial efficiency after 1000 h of continuous illumination without encapsulation. This work provides a promising universal method to regulate the energy level of carbon electrodes for C-PSCs and paves the way for more efficient, stable, and scalable solar technologies toward commercialization.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2026-41-03-07)
Conventional lignin-based carbons typically have sluggish ion transport and a limited number of active sites, which restrict their performance as electrodes in supercapacitors. A Moiré-like morphology was engineered by the in-situ deposition of lignin carbon onto DVD matrix onto lignin carbon for the fabrication of a photo-assisted supercapacitor (PASC). The Moiré-like structure modulates light propagation across different frequencies by dispersion effects, thereby increasing surface light absorption and improving the electrochemical performance of the PASC. Under illumination, the carbon has a specific capacitance of 253.5 F g−1 at 0.5 A g−1, corresponding to a 35.6% improvement over one without this grating surface (186.9 F g−1). A symmetrical capacitor using this material has an areal capacitance of 58.84 mF cm−2 and an energy density of 4.46 Wh kg−1 at a power density of 365.2 W kg−1, maintaining 85.2% of its initial capacitance after 5000 cycles, thus demonstrating excellent cycling stability. This work suggests a cost-effective strategy to simultaneously improve the light-harvesting ability and capacitive performance of PASCs.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2025-5-3)
In recent years, numerous single-atom catalysts (SACs) have been synthesized to activate persulfate (PS) by a non-radical pathway because of its high selectivity, and activity for the catalyst. Metal-nitrogen-carbon (M-Nx-C) has been identified as the key active site in SACs. Although methods for preparing SACs have been extensively reported, a systematic summary of the direct construction of M-Nx-C, especially unconventional metal-nitrogen-carbon (UM-Nx-C, x≠4), on SACs for PS non-radical activation has still not been reported. The role of the M-Nx-C active sites on PS non-radical activation is discussed and methods for the formation of M-Nx-C and UM-Nx-C active sites in SACs and the effect of catalyst carriers such as carbon nitride (g-C3N4), MOFs, COFs, and other carbon materials are reviewed. Direct and indirect methods, especially for UM-Nx-C active site formation, are also elaborated. Factors affecting the formation of a M-Nx-C active site on SACs are also discussed. Prospects for the use of M-Nx-C active sites for the non-radical activation of PS by SACs to remove organic contaminants from wastewater are evaluated.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2024-39-05-10)
The hydrogen evolution reaction (HER) is a promising way to produce hydrogen, and the use of non-precious metals with an excellent electrochemical performance is vital for this. Carbon-based transition metal catalysts have high activity and stability, which are important in reducing the cost of hydrogen production and promoting the development of the hydrogen production industry. However, there is a lack of discussion regarding the effect of carbon components on the performance of these electrocatalysts. This review of the literature discusses the choice of the carbon components in these catalysts and their impact on catalytic performance, including electronic structure control by heteroatom doping, morphology adjustment, and the influence of self-supporting materials. It not only analyzes the progress in HER, but also provides guidance for synthesizing high-performance carbon-based transition metal catalysts.
Transactions of Nonferrous Metals Society of China (中国有色金属学报)•2025•DOI: 10.1016/S1003-6326(25)67014-2
The effects of adding a novel Al−3Ti−4.35La master alloy and Nd and heat treatment on the microstructure and mechanical properties of Al−7Si alloy were investigated. The results showed that the secondary dendrite arm spacing of α-Al in the as-cast Al−7Si alloy was refined from 18.3 to 11.9 μm after modification with 0.2 wt.% Al−Ti−La and 0.03 wt.% Nd, and the length of eutectic Si was reduced from 8.6 to 5.0 μm. After heat treatment at 535 °C for 3 h followed by 165 °C for 3 h, the morphology of the eutectic Si became more rounded, and the size decreased. The microhardness, ultimate tensile strength, and elongation were HV 66.1, 184.9 MPa, and 24.4%, respectively, which increased by 24.2%, 11.6%, and 194.0% compared to the as-cast state. The addition of Al−3Ti−4.35La master alloy and Nd can reduce the nucleation temperature of eutectic Si in Al−7Si, thereby suppressing its growth. Notably, the Ti2(Al,Si)20(La,Nd) phase formed in the Al−7Si alloy after the addition of Al−Ti−La and Nd adhered to or coexisted near the eutectic Si particles, inhibiting their growth.
Transactions of Nonferrous Metals Society of China (中国有色金属学报)•2025•DOI: 10.1016/S1003-6326(25)67022-1
Based on the application requirements for porous dental implants, four porous structures of gyroid, RD (rhombic dodecahedron), cubic, and CHC (three identical cylinders hollow cubic) for porous titanium implants have been designed and fabricated using selective laser melting (SLM) technology. Typically, the unit cell dimensions range from 0.5 to 1.6 mm, with pore diameters between 300 and 900 µm, achieving porosities of 60%−80%. The influence of porous structures with small unit cell on scaffold formability and mechanical properties was investigated through compression, torsion tests as well as finite element simulations. Consequently, gyroid scaffolds exhibit optimal formability with the lowest porosity and pore deviation. With the same porosity, gyroid and RD scaffolds exhibit lower compressive strength than cubic and CHC scaffolds, yet their torsional properties show an inverse relationship. Moreover, gyroid scaffolds possess the highest torque but the lowest compressive strength and elastic modulus. The gyroid scaffold with 60% porosity shows a modulus of 3.96 GPa, matching bone modulus of 0−30 GPa. Its compressive strength reaches 176.3 MPa, exceeding that of bone by 100 MPa. Additionally, the torque for the d4.0 mm implant is 2.22 N·m, approaching the FDA safe torque of 2.3 N·m. Therefore, the gyroid represents the most ideal structure for porous dental implants.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2025•DOI: 10.1088/1674-4926/25030012
In recent years, research advancements have highlighted the critical role of the A-site cation in determining the optoelectronic and physicochemical properties of organic–inorganic lead halide perovskites. Mixed-cation perovskites (MCPs) have been extensively used as absorber thin films in perovskite solar cells (PSCs), achieving high power conversion efficiencies (PCE) over 26%. The incorporation of mixed cations has led to a more optimal tolerance factor for the crystal structure, enhancing structural stability and providing additional functionalities to improve the chemical stability of the absorber thin films. However, mixed-cation perovskite absorbers often experience element and phase segregation, which can reduce device efficiency and operational lifespan. This segregation is a widespread phenomenon observed across various types of MCPs, whether in 2D or 3D structures. Therefore, understanding the fundamental causes of non-uniformity and phase segregation, as well as effective nanoscale regulatory strategies, is essential for enhancing the performance of PSCs. The development of high-quality MCPs with highly uniform cation distribution and stable phases is critical for addressing the stability challenges in PSCs.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2025•DOI: 10.1088/1674-4926/25030039
In this study, with the aim of achieving a high signal-to-noise ratio (SNR) in an electron-bombarded complementary metal−oxide−semiconductor (EBCMOS) imaging chip, we analyzed the sources of noise using principles from low-light-level imaging and semiconductor theory, and established a physical computational model that relates the electron-multiplication layer to the noise characteristics of an EBCMOS chip in a uniformly doped structure with a P-type substrate. We conducted theoretical calculations to analyze the effects on noise characteristics of the passivation layer material and thickness, P-substrate doping concentration, P-substrate thickness, incident electron energy, and substrate temperature. By comparing the characteristics of pixel noise, dark current, multiplication electron numbers, and SNR under various structures, we simulated optimized structural parameters of the device. Our simulation results showed that the noise characteristics of the device could be optimized using an Al2O3 passivation thickness of 15 nm and substrate temperature of 260 K, and by decreasing the doping concentration and thickness of the P-type substrate and increasing the incident electron energy. The optimized SNR were 252 e/e. And the substantial impact of dark current noise, primarily governed by interfacial defects, on the overall noise characteristics of the device. This research offers theoretical support to develop EBCMOS imaging chips with high gain and SNR.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2025•DOI: 10.1088/1674-4926/25040026
In this letter, we demonstrate the effect of γ irradiation on the lateral AlGaN/GaN Schottky barrier diodes (SBDs) with self-terminated recessed anode structure and low work-function metal tungsten (W) as anode. For a comprehensive evaluation of the radiation-resistance performance of the device, the total dose of γ irradiation is up to 100 kGy with irradiation time of 20 h. Attributed to the barrier lowering effect of the W/GaN interface induced by γ irradiation observed in the experiment, the extracted turn-on voltage (VON) defined at anode forward current of 1 mA decreases from 0.47 to 0.43 V. Meanwhile, benefiting from the reinforced Schottky interface treated by post-anode-annealing, a high breakdown voltage (BV) of 1.75 kV is obtained for the γ-irradiated AlGaN/GaN SBD, which shows the promising application for the deep-space radiation environment and promotes the development of radiation-resistance research for GaN SBDs.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2025•DOI: 10.1088/1674-4926/25040033
As artificial intelligence (AI) workloads escalate exponentially, ultra-thin, high-efficiency voltage regulator modules (VRMs) with exceptional power density become essential for backside-mounted configurations. High-density multiphase DC−DC converters are pivotal for implementing vertical power delivery (VPD) architectures in XPU platforms. Strategically positioning these converters beneath processors and maximizing spatial utilization enables core rail currents exceeding 2 kA while significantly reducing power distribution network (PDN) losses compared to conventional solutions. The VPD configuration elevates system-level energy efficiency with >100 W power saving per processor, yielding megawatt-scale savings in a datacenter that uses ~100 000 processors. The synergy of 48 V power conversion architectures and advanced packaging techniques enables the industry’s commitment to balancing computational demands with CO2 emission reduction and environmental sustainability. This paper discusses system architecture, layout geometry, and control strategies for multi-chip multi-phase DC−DC converters, comparing ring, chain, and net topologies, as well as independent and master-slave control schemes.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.04.006
To reveal the deterioration mechanism of coal-rock assemblages under chemical corrosion and dynamic loading, chemical corrosion and dynamic impact experiments were conducted. Under different chemical corrosion conditions, the weakening characteristics, observable characteristics, softening characteristics of the dynamic parameters, dynamic failure characteristics, dynamic failure forms and dynamic microscopic characteristics were analyzed. Under each corrosion condition, the dynamic elastic modulus, dynamic deformation modulus and dynamic peak intensity tended to decrease with immersing time. The dynamic elastic modulus, dynamic deformation modulus and dynamic peak intensity exhibited an inverted U-shaped trend. Under dynamic impact, the failure process of acidly corroded samples can be divided into the following stages: the initial stage, elastic energy accumulation stage, local failure of coal and secondary rock crack expansion stage, coal fragment ejection stage, rock spalling stage and complete instability stage. Under dynamic impact, failure modes exist: coal crushing failure, rock fragmenting failure, rock splitting failure and full splitting failure. After impact failure, sample fragments are distributed in powder, granular, cone and block forms. Based on Zhu-Wang-Tang nonlinear viscoelastic properties, a model considering chemical corrosion and impact damage was proposed. The combined effects of chemical and impact-induced damage on the dynamic mechanical properties of coal-rock assemblages were systematically analyzed.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.06.011
Coal wall stability is a critical factor influencing coal mining efficiency and threatens the safety of working faces, where irregular coal wall surfaces significantly affect the contact and support effectiveness of the support plate, thereby impacting stability. Through a combination of theoretical analysis, mechanical testing, and numerical simulations, this study establishes a mechanical model of irregular coal wall surfaces to investigate the effects of the undulation period and undulation height on coal wall failure characteristics. This research reveals the mechanical response mechanisms of irregular coal wall surfaces and proposes an innovative method to enhance coal wall stability by improving the supporting cushion material of the support plate, which was validated through numerical simulations. The results show that the undulation height and undulation period significantly influence the macroscopic mechanical parameters of the samples, with the undulation height exerting a more pronounced effect. The strength of the samples with undulating surfaces is approximately 50%–60% that of the samples with flat surfaces. The failure mode under uniaxial compression is predominantly tensile, resulting in long and slender block fragments with a characteristic “III”-shaped tensile fracture pattern. During the loading process, samples with undulating surfaces dissipate energy at all stages, with a greater proportion of energy dissipation occurring during the early loading stage because of structural damage and the formation of internal cracks. The surface compressive and tensile stresses are correlated with the curvature radius of the convex surface and the elastic modulus of the supporting plate. Reducing the elastic modulus of the supporting plate material can effectively alleviate the stress concentration at convex locations and increase the peak strength. This study provides theoretical foundations and technical references for the prevention and control of coal wall spalling in deep thick coal seam mining.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.06.004
In recent years, computational chemistry studies of chalcopyrite and pyrite flotation surfaces have advanced significantly, yet current methods are constrained by small system sizes and inadequate consideration of hydration and temperature effects, limiting their ability to replicate real flotation environments. In this study, we employed the self-consistent charge density functional tight-binding (SCC-DFTB) parameterization method to develop a parameter set, CuFeOrg, encompassing interactions among Cu, Fe, C, H, O, N, S, P, and Zn elements, to investigate surface interactions in large-scale flotation systems of chalcopyrite and pyrite. Validation through bulk modulus, atomic displacement, band structure, surface relaxation, surface Mulliken charge distribution, and adsorption tests of typical flotation reagents on mineral surfaces demonstrated that CuFeOrg achieves DFT-level accuracy while significantly outperforming DFT in computational efficiency. By constructing large-scale hydration systems of mineral surfaces, as well as systems incorporating combined mineral surface, flotation reagent, and hydration interactions, we more realistically reproduced actual flotation environments. Dynamic analysis results were consistent with mineral surface contact angle experiments. CuFeOrg lays the foundation for future studies of more complex and diverse chalcopyrite and pyrite flotation surface systems.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.07.006
Coal mine underground reservoir (CMUR) technology mitigates water scarcity in China's coal-rich western regions but lacks tailored solutions for steeply inclined coal seams. This study develops a novel framework of steeply inclined coal mine underground reservoirs (SICMUR), which is a paradigm shift from conventional CMUR that the coal seam itself serves as the reservoir floor, challenging conventional designs due to depth-dependent permeability and mechanical constraints. Triaxial mechanical-seepage tests on Xinjiang Wudong coal samples (100, 200, 300 m depths) revealed a 3.5 MPa triaxial strength increase per 100 m depth and a 58-fold post-peak permeability surge at 300 versus 100 m. Similar model simulations revealed mining-induced stress redistribution and significant deformation effects, particularly subsidence and water-conducting fractures during lower coal seam mining. Results indicate a minimum 40 m safety distance between reservoirs and lower coal seams. Critical construction parameters were investigated for Wudong mine SICMUR as collapse zone heights (9.9–12.31 m) and water-conducting fracture zone heights (31.96–37.40 m). This work systematically bridges SICMUR concepts to field implementation, offering a framework for water preservation in steeply inclined mining while addressing safety concerns, providing a new approach for water reservation in steeply inclined coal mining.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.08.010
The spatiotemporal characterization of plume sedimentation and microorganisms is critical for developing plume ecological monitoring models. To address the limitations of traditional methods in obtaining high-quality sediment, a novel sampling system with 6000 m operational capability and three-month endurance was developed. It is equipped with three sediment samplers and a set of formaldehyde preservation solution injection devices. The system is controlled by a low-power, timing-triggered controller. To investigate low-disturbance rheological mechanisms, gap-controlled rheological tests were conducted to optimize the structural design of the sampling and sealing assembly. Stress-controlled shear rheological tests were employed to investigate the mechanisms governing yield stress in sediments under varying temperature conditions and boundary roughness. Additionally, the coupled Eulerian-Lagrangian (CEL) method and sediment rheological constitutive models were employed to simulate tube-soil interaction dynamics and sediment disturbance. The radial heterogeneity of sediment disturbance and friction variation of the sampling tube were revealed. The tube was completely "plugged" at a penetration depth of 261 mm, providing critical data support for penetration depth parameters. The deep-sea pressure test and South China Sea field trials demonstrated the system's capability to collect and preserve quantitative time-series sediment samples with high fidelity.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.09.008
To investigate the influence of non-uniform water distribution on the mechanical properties and failure behavior of red sandstone, we designed five immersion heights and durations to achieve varying non-uniform water distribution states. Uniaxial compression tests were conducted on red sandstone under these conditions. The effects of non-uniform water distribution on deformation, failure, strength, and energy characteristics of red sandstone were analyzed. The impact of non-uniform water distribution on the intensity of rock failure was discussed, and the failure mechanism under non-uniform water distribution was revealed. The hazards of low immersion heights on underground rock structures were analyzed. The results demonstrate that peak strength and elastic modulus of red sandstone exhibit high sensitivity to immersion height, with reductions of 38% and 23% respectively even at L=1/50H. Water immersion reduces both energy storage capacity and energy dissipation capability of red sandstone. The immersion height and duration influence the failure mode of red sandstone by controlling the migration and separation of dry-wet interfaces. Low immersion height poses significant risks to underground rock structures (e.g., a 38% strength reduction when L=1/50H), and the concentration degree of water non-uniform distribution is the key factor in assessing the weakening effect of water on rocks.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.10.011
To investigate groundwater influence on stability and rockburst mechanism of deep hard-rock rectangular tunnels, water-immersed treatment and uniaxial compressive acoustic emission (AE) experiments were conducted on rectangular tunnel specimens. Energy dissipation characteristics, AE evolution characteristics and damage evolution characteristics of rectangular tunnels were analysed under water-immersed condition. Under water-immersed condition, tunnel specimens were quite sensitive to water. Average peak stress and average peak strain energy exhibited negative exponential decay with water-immersed time. Among them, after 12 d of water immersion, average peak stress of specimens decreased by 28%. Average total strain energy decreased by 70%. Average elastic strain energy decreased by 71% and average dissipated strain energy decreased by 68%. After 62 d of water immersion, average peak stress of specimens decreased by 34%. Average total strain energy decreased by 78%. Average elastic strain energy decreased by 79% and average dissipated strain energy decreased by 75%. Water weakened bonding among mineral particles. Moreover, it undermined load-bearing capacity and diminished energy-storage properties. Under high stress, massive releasable elastic strain energy stored in natural specimens within pre-peak stage may abruptly release after peak stress. This caused rapid crack development and connection in specimens. During accumulation and release of elastic strain energy, initial failure typically occurred at sidewalls. This failure location was not affected by water. Compared with natural specimens, specimens immersed in water for 62 d had the lowest peak values of cumulative amplitude, cumulative AE energy and cumulative AE count. After 62 d of water immersion, peak values of cumulative amplitude, cumulative AE energy and cumulative AE count of specimens decreased by 84%, 97% and 99%. Compared with AE damage model, fitting degree of energy damage model was higher. For natural specimens, fitting degree of energy damage model was 0.96. For specimens immersed in water for 12 d, fitting degree of energy damage model was 0.96. For specimens immersed in water for 62 d, fitting degree of energy damage model was 0.72. Therefore, an energy damage model had more remarkable applicability and reliability. By establishing dynamic mapping relationship between energy and damage in the model, accuracy of rockburst early warning has been significantly improved. This provided scientific basis for support structure design of rectangular tunnels and regulation of high strain energy.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.10.008
Deep mining is imperative, and the consequent coal and gas outburst disasters triggered during coal uncovering are becoming increasingly severe. Therefore, this study investigated the mechanical mechanisms of outburst instability from three dimensions: experiment, numerical simulation, and field application. Based on physical simulation tests with different outburst pore diameter, it was found that the gas pressure relief rate, gas emission volume, and outburst dynamic phenomena increase with outburst pore diameter. The migration patterns of the gas-solid two-phase flow evolved over time approximately into suspension flow, plug flow, dune flow, and stratified flow. The dominant influence of gas-driven tensile failure was amplified by uncovering coal area. The employment of the “fluid-solid-damage” coupling model revealed that coal damage, gas emission volume, deflection angle of outburst hole, roof displacement, maximum horizontal tensile stress, the horizontal tensile stress zone, the peak seepage force, and the damage zone all increased with uncovering coal areas. At the gas pressure of 0.74 MPa, when the uncovering coal areas were 3.189, 4.754 and 6.225 m, the total gas emission volumes were 4.72×10−4, 16.83×10−4, and 17.67 m2/s, deflection angles of outburst hole were 150.79°, 152.89° and 158.66°, the maximum roof displacements were 0.044, 0.046, and 0.325 m, and the peak seepage force were 0.85, 1.27, and 1.46 MPa/m, respectively. The regions of coal failure calculated by tensile failure criterion largely coincided with those calculated by the mixed failure criterion, far greater than those calculated by the shear failure criterion. As the increase of uncovering coal area, tensile weights of 80.72%, 89.78%, and 93.01%, respectively. Comparisons with field outburst cases showed that both gas emission volume and outburst hole deflection angle reflected the tensile failure of coal. The mechanical instability process of outbursts under the influence of uncovering coal area and gas pressure was analyzed, developing the progressive cyclical method of coal uncovering, which provided a novel approach for the achievement of safe coal mining.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.10.002
Retrogressive landslides in sensitive clays pose significant risks to nearby infrastructure, as natural toe erosion or localized disturbances can trigger progressive block failures. While prior studies have largely relied on two-dimensional (2D) large-deformation analyses, such models overlook key three-dimensional (3D) failure mechanisms and variability effects. This study develops a 3D probabilistic framework by integrating the Coupled Eulerian–Lagrangian (CEL) method with random field theory to simulate retrogressive landslides in spatially variable clay. Using Monte Carlo simulations, we compare 2D and 3D random large-deformation models to evaluate failure modes, runout distances, sliding velocities, and influence zones. The 3D analyses captured more complex failure modes—such as lateral retrogression and asynchronous block mobilization across slope width. Additionally, the 3D analyses predict longer mean runout distances (13.76 vs. 11.92 m), wider mean influence distance (11.35 vs. 8.73 m), and higher mean sliding velocities (4.66 vs. 3.94 m/s) than their 2D counterparts. Moreover, 3D models exhibit lower coefficients of variation (e.g., 0.10 for runout distance) due to spatial averaging across slope width. Probabilistic hazard assessment shows that 2D models significantly underpredict near-field failure probabilities (e.g., 48.8% vs. 89.9% at 12 m from the slope toe). These findings highlight the limitations of 2D analyses and the importance of multi-directional spatial variability for robust geohazard assessments. The proposed 3D framework enables more realistic prediction of landslide mobility and supports the design of safer, risk-informed infrastructure.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.12.008
Microseismic (MS) monitoring is an effective technique to detect mining-induced rock fractures. However, recognizing grouting-induced signals is challenging due to complex geological conditions in deep rock plates. Therefore, a hybrid model (WM-ResNet50) integrating data enhancement, a deep convolutional neural network (CNN), and convolutional block attention modules (CBAM) was proposed. Firstly, an MS system was established at the Xieqiao coal mine in Anhui Province, China. MS waveforms and injection parameters were acquired during grouting. Secondly, signals were categorized based on time–frequency characteristics to build a dataset, which was divided into training, validation, and test sets at a ratio of 4:1:1. Subsequently, the performance of WM-ResNet50 was evaluated based on indices such as individual precision, total accuracy, recall, and loss function. The results indicated that WM-ResNet50 achieved an average recognition accuracy of 94.38%, surpassing that of a simple CNN (90.04%), ResNet18 (91.72%), and ResNet50 (92.48%). Finally, WM-ResNet50 was applied to monitor the whole process at laboratory tests and field cases. Both results affirmed the feasibility and effectiveness of MS inversion in predicting actual slurry diffusion ranges within deep rock layers. By comparison, it was revealed that the MS sources classified by WM-ResNet50 matched grouting records well. A solution to address insufficient diffusion under long-borehole grouting has been proposed. WM-ResNet50's accuracy was validated through in-situ coring and XRD analysis for cement-based hydration products. This study provides a beneficial reference for similar rock signal processing and in-field grouting practices.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-024-2971-z
The equilibrium phase relations of the CaO–SiO2–TiO2–5wt%Fe3O4 system were experimentally investigated at 1400°C in air. High-temperature equilibration-quenching techniques were employed in an electric MoSi2 resistance heated furnace, with phase composition analysis conducted using an electron probe microanalyzer and X-ray diffraction. A single liquid region, liquid–solid phase equilibria regions (including liquid–tridymite, liquid–rutile, liquid–perovskite, and liquid–wollastonite), and three-phase equilibria regions of liquid–tridymite–rutile and liquid–rutile–perovskite were found. The 1400°C isothermal sections of the CaO–SiO2–TiO2–5wt%Fe3O4 system in air were projected. The present experimental results exhibited good agreement with the calculation results obtained from FactSage.
Chinese Journal of Mechanical Engineering•2025•DOI: 10.1186/s10033-025-01350-3
The fused quartz hemispherical resonator is the core component of the hemispherical resonator gyroscope. It features a complex shape and is made from a material that is difficult to process. Scratches are easily introduced during grinding, potentially degrading the mass-stiffness-damping symmetry; however, the underlying mechanisms of this influence have not been fully understood. This paper aims to investigate the effects of scratch defects on the frequency splitting and quality factor of the hemispherical resonator. First, finite element models of the hemispherical resonator with scratches are established. Then, the effects of the mass-stiffness factor, as well as the latitude and length of the scratches, on frequency splitting are analyzed. Furthermore, the impacts of latitude, length, and the first four harmonics of the unbalanced mass caused by scratches on thermoelastic damping and anchor loss are examined. Simulation results indicate that scratches above 55° latitude cause frequency splitting solely due to stiffness changes. Frequency splitting caused by scratches of the same size on the inherent rigidity shaft at the rim is approximately 50% of that near the transition fillet. Frequency splitting varies linearly with the volume of material removed by scratches. Scratches have little effect on thermoelastic damping. The first three harmonics of the unbalanced mass due to scratches at the rim are the primary contributors to anchor loss. Finally, focused ion beam trimming experiments are conducted at different locations on the hemispherical resonator. The trends observed in the experimental results are consistent with the simulation results. This work provides guidance for evaluating the impact of scratches on the performance of hemispherical resonators and for developing appropriate trimming processes.
Chinese Journal of Mechanical Engineering•2025•DOI: 10.1186/s10033-025-01273-z
As a crucial component of intelligent chassis systems, air suspension significantly enhances driver comfort and vehicle stability. To further improve the adaptability of commercial vehicles to complex and variable road conditions, this paper proposes a linear motor active suspension with quasi-zero stiffness (QZS) air spring system. Firstly, a dynamic model of the linear motor active suspension with QZS air spring system is established. Secondly, considering the random uncertainties in the linear motor parameters due to manufacturing and environmental factors, a dynamic model and state equations incorporating these uncertainties are constructed using the polynomial chaos expansion (PCE) method. Then, based on H2 robust control theory and the Kalman filter, a state feedback control law is derived, accounting for the random parameter uncertainties. Finally, simulation and hardware-in-the-loop (HIL) experimental results demonstrate that the PCE-H2 robust controller not only provides better performance in terms of vehicle ride comfort compared to general H2 robust controller but also exhibits higher robustness to the effects of random uncertain parameters, resulting in more stable control performance.
Chinese Journal of Mechanical Engineering•2025•DOI: 10.1186/s10033-025-01217-7
The high-temperature oxidation resistance of AISI 321 stainless steel used in solar thermal power heat exchangers determines its service life. In this study, aluminizing and subsequent laser shock peening (LSP) treatments were employed to improve the high-temperature oxidation resistance of AISI 321 stainless steel at 620 °C. These two treatments decreased the oxidation rate of AISI 321 steel. Specifically, the optimal oxidation resistance was observed in aluminized steel before oxidation for 144 h owing to the increased entropy of the LSP-treated specimen. After 144 h, LSP-treated steel achieved the best oxidation resistance because of the formation of a protective α-Al2O3 film. Moreover, the large amount of subgrain boundaries formed on the aluminized layer of the LSP-treated samples could act as short-circuit paths for the outward diffusion of Al, facilitating the rapid nucleation of α-Al2O3. Meanwhile, the aluminized layer could isolate the contact between the oxidation environment and matrix, thereby decreasing the oxidation rate. Furthermore, the minimum oxidation parabolic constant was calculated for LSP-treated steel (6.45787 × 10−14), which was 69.18% and 36.36% that of aluminized and 321 steel, respectively, during the entire oxidation process. Therefore, the combination of aluminizing and LSP treatments can improve the high-temperature oxidation resistance of 321 stainless steel, providing a new idea for its surface treatment to achieve a long service life at high temperatures.
Chinese Journal of Mechanical Engineering•2025•DOI: 10.1186/s10033-024-01172-9
Tracking control of tendon-driven manipulators has become a prevalent research area. However, the existence of flexible elastic tendons generates substantial residual vibrations, resulting in difficulties for trajectory tracking control of the manipulator. This paper proposes the radial basis function neural network adaptive hierarchical sliding mode control (RBFNNA-HSMC) method, which combines the dynamic model of the elastic tendon-driven manipulator (ETDM) with radial basis neural network adaptive control and hierarchical sliding mode control technology. The aim is to achieve trajectory tracking control of ETDM even under conditions of model inaccuracy and disturbance. The Lyapunov stability theory demonstrates the stability of the proposed RBFNNA-HSM controller. In order to assess the effectiveness and adaptability of the proposed control method, simulations and experiments were performed on a two-DOF ETDM. The RBFNNA-HSM method shows superior tracking accuracy compared to traditional model-based HSM control. The experiment shows that the maximum tracking error for ETDM double-joint trajectory tracking is below 2.593×10-3 rad and 1.624×10-3 rad, respectively.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6137-6
Aerodynamic drag is the dominant factor contributing to energy consumption as the operational speed of high-speed trains increases, necessitating effective aerodynamic optimization strategies. This study investigates the aerodynamic characteristics of the bogie region under two bogie fairing configurations: baseline bogie fairing (BBF) and full bogie fairing (FBF). Both stationary and rotating wheelset conditions are considered. Wind tunnel experiments were conducted on a full-scale bogie model equipped with a wheelset drive system to simulate wheelset rotation. Additionally, numerical simulations were employed to analyze flow structures. Results indicate that the FBF configuration promotes a more uniform front-to-rear pressure distribution in the bogie region. The rotation of the wheelset notably affects the airflow near the wheels and extends its influence throughout the entire bogie region. Specifically, wheelset rotation reduces drag by 6.38% in the BBF configuration but increases drag by 3.5% in the FBF configuration. Further analysis reveals that, in the FBF configuration, aerodynamic drag primarily originates from the wheelsets. The rotating wheelset increases the aerodynamic drag by 18.8% for the rear wheelset, which is attributed to the shift in the pressure curve on the wheelset in the rotating direction. Therefore, the impact of wheelset rotation on aerodynamic characteristics should not be overlooked.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6121-1
Additive manufacturing (AM) of SiCP/Al composites has shown significant potential for expanding the application of aluminum matrix composites (AMCs) due to their outstanding mechanical properties and wear performance. However, conventional mechanically mixed powders for AM are limited due to the possible powder agglomeration and poor fluidity. In this study, the spherical SiCP/AlSi10Mg composite powders prepared by spray granulation were employed to fabricate SiCP-reinforced AlSi10Mg composites using laser powder bed fusion (LPBF). The impacts of laser power on microstructure evolution and wear properties of composites were systematically investigated. The results indicated that an in-situ reaction between the aluminum matrix and SiCP during the LPBF process, resulted in the formation of particle-like and strip-like strengthening phase Al4SiC4. By adjusting the laser power (from 270 W to 350 W) to change the ratio of SiCP to Al4SiC4, micro-defects could be effectively limited, and wear performance could be improved. Consequently, with an optimized ratio of SiCP to Al4SiC4, the composite exhibited a mixed strengthening mechanism caused by the SiCP and Al4SiC4 reinforcing phases. At a laser power of 310 W, the sample exhibited minimal porosity with a microhardness value reaching 265.38HV, while maintaining relatively low average friction coefficient and wear rate. In addition, compared with other studies, the hardness obtained was superior to that of the AlSi10Mg and other reported SiCP/AlSi10Mg composites with similar volume fractions using the mixed powders.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6099-8
Potassium-ion batteries (KIBs) are rising as a noteworthy contender to lithium-ion batteries (LIBs), particularly for large-scale applications, driven by the natural abundance and cost-effectiveness of potassium resource. Yet, lacking anodes which can reversibly accommodate the larger K+ currently poses a critical development hurdle, highlighting an urgent need for innovative solutions. Herein, porous ZnO-SnO2-graphene-carbon (ZTO-G-C) nanofibers are presented, featuring amorphous SnO2 and ZnO nanoparticles homogeneously dispersed within a carbon matrix, with the strategic graphene incorporation for enhanced performance. Employing an adjustable and straightforward electrospinning method, the nanofibers were crafted to achieve a stable fibrous architecture. When evaluated as KIB anodes, the ZTO-G-C nanofibers demonstrated remarkable cycling stability (retaining 230.82 mA·h/g over 100 cycles at 100 mA/g), and rate capability (184.78 mA·h/g at 1 A/g). This outstanding performance is due to the synergistic interaction among all active components, collectively enhancing the structural stability against volume expansion during K+ intercalation, facilitating efficient charge transport, and delivering exceptional cyclability, capacity, and rate performance. Moreover, the intrinsic pseudocapacitive behavior stemming from the porous carbon substrate of ZTO-G-C further boosts its overall K-storage capacity. It is anticipated that the insights gained from this study offer fresh perspectives for developing next-generation high-performance KIB anodes.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-025-3149-z
Novel hydrogen storage materials have propelled progress in hydrogen storage technologies. Magnesium hydride (MgH2) is a highly promising candidate. Nevertheless, several drawbacks, including the need for elevated thermal conditions, sluggish dehydrogenation kinetics, and high thermodynamic stability, limit its practical application. One effective method of addressing these challenges is catalyst doping, which effectively boosts the hydrogen storage capability of Mg-based materials. Herein, we review recent advancements in catalyst-doped MgH2 composites, with particular focus on multicomponent and high-entropy catalysts. Structure–property relationships and catalytic mechanisms in these doping strategies are also summarized. Finally, based on existing challenges, we discuss future research directions for the development of Mg-based hydrogen storage systems.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-025-3201-z
The performance of the fuel electrode in a solid oxide electrolysis cell (SOEC) is crucial to facilitating fuel gas electrolysis and is the key determinant of overall electrolysis efficiency. Nevertheless, the commercialization of integrated CO2–H2O electrolysis in SOEC remains constrained by suboptimal catalytic efficiency and long-term stability limitations inherent to conventional fuel electrode architectures. A novel high-entropy Sr2FeTi0.2Cr0.2Mn0.2Mo0.2Co0.2O6−δ (SFTCMMC) was proposed as a prospective electrode material of co-electrolysis in this work. The physicochemical properties and electrochemical performance in the co-electrolysis reaction were investigated. Full cell is capable of electrolyzing H2O and CO2 effectively with an applied voltage. The effects of temperature, H2O and CO2 concentrations, and applied voltage on the electrochemical performance of Sc0.18Zr0.82O2−δ (SSZ)-electrolyte supported SOEC were investigated by varying the operating conditions. The SOEC obtains a favorable electrolysis current density of 1.47 A·cm−2 under co-electrolysis condition at 850°C with 1.5 V. Furthermore, the cell maintains stable performance for 150 h at 1.3 V, and throughout this period, no carbon deposition is detected. The promising findings suggest that the high-entropy SFTCMMC perovskite is a viable fuel electrode candidate for efficient H2O/CO2 co-electrolysis.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-024-2977-6
Large-scale underground projects need accurate in-situ stress information, and the acoustic emission (AE) Kaiser effect method currently offers lower costs and streamlined procedures. In this method, the accuracy and speed of Kaiser point identification are important. Thus, this study aims to integrate chaos theory and machine learning for accurately and quickly identifying Kaiser points. An intelligent model of the identification of AE partitioned areas was established by phase space reconstruction (PSR), genetic algorithm (GA), and support vector machine (SVM). Then, the plots of model classification results were made to identify Kaiser points. We refer to this method of identifying Kaiser points as the partitioning plot method based on PSR–GA–SVM (PPPGS). The PSR–GA–SVM model demonstrated outstanding performance, which achieved a 94.37% accuracy rate on the test set, with other evaluation metrics also indicating exceptional performance. The PPPGS identified Kaiser points similar to the tangent-intersection method with greater accuracy. Furthermore, in the feature importance score of the classification model, the fractal dimension extracted by PSR ranked second after accumulated AE count, which confirmed its importance and reliability as a classification feature. The PPPGS was applied to in-situ stress measurement at a phosphate mine in Guizhou Weng’an, China, to validate its practicability, where it demonstrated good performance.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-024-2943-3
Fe–Ga sheets with large magnetostriction are required for improving the conversion efficiency under the ultra-high frequency magnetic field. Trace Tb element doping can simultaneously improve the magnetostriction and ductility of Fe–Ga alloy. However, the impact of trace Tb doping on the microstructure and magnetostriction of Fe–Ga thin sheets is an open question. In this paper, the effects of trace Tb addition on the secondary recrystallization and magnetostriction of Fe–Ga thin sheets are systematically studied by comparing the characteristics evolution of precipitation, texture, and nanoinclusions. The results indicate that trace Tb addition accelerates the secondary recrystallization of Goss texture due to the combined action of the bimodal size distributed precipitates, smaller grains, and more HEGBs in primary recrystallization. After quenching at 900°C, the magnetostriction value in 0.07at%Tb-doped Fe81Ga19 thin sheets increases by 30% to that of Fe81Ga19 thin sheets. The increase in magnetostriction is attributed to the decrease in the number of Tb-rich precipitates and the higher density of the nanometer-sized modified-D03 inclusions induced by the dissolving of trace Tb elements after quenching. These results demonstrate a simple and efficient approach for preparing Fe–Ga thin sheets with a large magnetostrictive coefficient by a combination of trace RE element addition and conventional rolling method.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-024-2935-3
This work reveals the significant effects of cobalt (Co) on the microstructure and impact toughness of as-quenched high-strength steels by experimental characterizations and thermo-kinetic analyses. The results show that the Co-bearing steel exhibits finer blocks and a lower ductile–brittle transition temperature than the steel without Co. Moreover, the Co-bearing steel reveals higher transformation rates at the intermediate stage with bainite volume fraction ranging from around 0.1 to 0.6. The improved impact toughness of the Co-bearing steel results from the higher dense block boundaries dominated by the V1/V2 variant pair. Furthermore, the addition of Co induces a larger transformation driving force and a lower bainite start temperature (BS), thereby contributing to the refinement of blocks and the increase of the V1/V2 variant pair. These findings would be instructive for the composition, microstructure design, and property optimization of high-strength steels.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01577-0
Harvesting the immense and renewable osmotic energy with reverse electrodialysis (RED) technology shows great promise in dealing with the ever-growing energy crisis. One key challenge is to improve the output power density with improved trade-off between membrane permeability and selectivity. Herein, polyelectrolyte hydrogels (channel width, 2.2 nm) with inherent high ion conductivity have been demonstrated to enable excellent selective ion transfer when confined in cylindrical anodized aluminum pore with lateral size even up to the submillimeter scale (radius, 0.1 mm). The membrane permeability of the anti-swelling hydrogel can also be further increased with cellulose nanofibers. With real seawater and river water, the output power density of a three-chamber cell on behalf of repeat unit of RED system can reach up to 8.99 W m−2 (per unit total membrane area), much better than state-of-the-art membranes. This work provides a new strategy for the preparation of polyelectrolyte hydrogel-based ion-selective membranes, owning broad application prospects in the fields of osmotic energy collection, electrodialysis, flow battery and so on.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01564-5
Formamidinium lead bromide (FAPbBr3) perovskite nanocrystals (NCs) are promising for display and lighting due to their ultra-pure green emission. However, the thermal quenching will exacerbate their performance degradation in practical applications, which is a common issue for halide perovskites. Here, we reported the heat-resistant FAPbBr3 NCs prepared by a ligand-engineered room-temperature synthesis strategy. An aromatic amine, specifically β-phenylethylamine (PEA) or 3-fluorophenylethylamine (3-F-PEA), was incorporated as the short-chain ligand to expedite the crystallization rate and control the size distribution of FAPbBr3 NCs. Employing this ligand engineering approach, we synthesized high quality FAPbBr3 NCs with uniform grain size and reduced long-chain alkyl ligands, resulting in substantially suppressed thermal quenching and enhanced carrier transportation in the perovskite NCs films. Most notably, more than 90% of the room temperature PL intensity in the 3-F-PEA modified FAPbBr3 NCs film was preserved at 380 K. Consequently, we fabricated ultra-pure green EL devices with a room temperature external quantum efficiency (EQE) as high as 21.9% at the luminance of above 1,000 cd m−2, and demonstrated less than 10% loss in EQE at 343 K. This study introduces a novel room temperature method to synthesize efficient FAPbBr3 NCs with exceptional thermal stability, paving the way for advanced optoelectronic device applications.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01539-6
Monitoring minuscule mechanical signals, both in magnitude and direction, is imperative in many application scenarios, e.g., structural health monitoring and robotic sensing systems. However, the piezoelectric sensor struggles to satisfy the requirements for directional recognition due to the limited piezoelectric coefficient matrix, and achieving sensitivity for detecting micrometer-scale deformations is also challenging. Herein, we develop a vector sensor composed of lead zirconate titanate-electronic grade glass fiber composite filaments with oriented arrangement, capable of detecting minute anisotropic deformations. The as-prepared vector sensor can identify the deformation directions even when subjected to an unprecedented nominal strain of 0.06%, thereby enabling its utility in accurately discerning the 5 μm-height wrinkles in thin films and in monitoring human pulse waves. The ultra-high sensitivity is attributed to the formation of porous ferroelectret and the efficient load transfer efficiency of continuous lead zirconate titanate phase. Additionally, when integrated with machine learning techniques, the sensor's capability to recognize multi-signals enables it to differentiate between 10 types of fine textures with 100% accuracy. The structural design in piezoelectric devices enables a more comprehensive perception of mechanical stimuli, offering a novel perspective for enhancing recognition accuracy.