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🏛️ Key Research Academy20 Indexed Works

Harbin Institute of Technology

Verified scientific contributions, CAS laboratory outputs, clinical trial papers, and engineering breakthroughs produced by researchers and faculty affiliated with Harbin Institute of Technology.

China Foundry2026

Microstructure and mechanical properties evolution of near-β alloy Ti-4Al-6Cr-5Mo-5Nb-xTa

Authors: Jia-qi Hao, Hong-ze Fang, Xing-fang Xue, Ji-chang Yu, Bo-bo Li, Bao-hui Zhu, Rui-run Chen

To meet the aerospace industry’s demand for aircraft featuring high thrust-to-weight ratios and lightweight structures capable of operating in complex service environments, β titanium alloys with high specific strength and good plasticity have become a current research hotspot in the development of domestic fasteners. Based on the calculated Mo equivalent, the alloy composition Ti-4Al-6Cr-5Mo-5Nb is classified as a near-β titanium alloy within the titanium alloy design space. The microstructure is further controlled by adding alloy element Ta with a mass fraction of 0.4wt.%-2.0wt.%. Research results indicate that Ta dissolves completely in the matrix without forming new phases within the investigated range. As the Ta content increases, the proportion of the β phase increases significantly, the β grain diameter decreases markedly from 2.4 mm to 0.4 mm, and the α phase gradually coarsens. When adding 1.6wt.% Ta, the tensile strength and fracture toughness of the alloy reach the peak values of 735 MPa and 55 MPa·m1/2, respectively.

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China Foundry (中国铸造 - 英文版)2026

Influence of Nb addition on microstructure evolution and superplastic behavior of Ti-5Al-5Mo-5Cr-2Zr-xNb titanium alloy at 923 K

Authors: Shi-chen Sun, Hong-ze Fang, Jia-qi Hao, Bao-hui Zhu, Xian-fei Ding, Rui-run Chen

Ti-5Al-5Mo-5Cr-2Zr-xNb with different Nb (abbreviated as Ti-5552-xNb, x=3, 6, 9, 12, wt.%) contents were stretched at 923 K to study their superplastic behavior and mechanical properties below recrystallization temperature. The microstructure of as-cast Ti-5552-xNb alloy is consisted of a single β phase, and the β grain size increases slightly with the increase of Nb content. The thermal effect in the process of high temperature drawing leads to the precipitation of α phase. The addition of Nb in Ti-5552 titanium alloys reduces the α/β phase transformation temperature, which causes a decrease in the volume fraction of α phase. Reducing the α phase content reduces incompatibility, but too low a proportion of α phase will lead to premature fracture, so tensile strength and plasticity firstly increase and then decrease. The results show that Ti-5552-9Nb titanium alloy shows the best tensile strength (307.2 MPa) and superplasticity (106%). The superplastic mechanism of Ti-5552-9Nb alloy is mainly caused by relative sliding of β grain boundaries and dislocation movement.

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China Foundry2026

Titanium alloy with synergistic enhancement of strength and toughness based on molybdenum equivalent design: Microstructure evolution and strengthening-toughening mechanism

Authors: Yi-li Li, Hong-ze Fang, Rui-run Chen, Jia-qi Hao, Bao-hui Zhu, Jing-jie Guo

The traditional "trial and error" microstructural control method, with high cost and low efficiency, has become a key issue restricting the development of ultra-high strength and toughness titanium alloys. This study adopts the molybdenum equivalent (Mo[eq]) method to rapidly design Ti-xMo-4Al-4Zr-3Nb-2Cr-1Fe alloys (x=5-9). The as-cast alloys with different Mo[eq] exhibit a single peak of the β phase in XRD. The β grains of 5Mo alloy (the lowest Mo[eq]) exhibit elongated columnar grain characteristics. As the Mo[eq] increases, the β grains transition towards a more equiaxed form, resulting in a decrease in aspect ratio and a reduction in grain size. As the Mo[eq] increases, the α phase content gradually decreases and the α phase is almost unobservable in 9Mo alloy (the highest Mo[eq]). The α phase in 5Mo alloy exhibits short rod-shaped shapes with an average length of about 2.4 μm, while the α phase in 6Mo alloy shows an equiaxed and short rod shapes with the smallest size. The strength, plasticity, and toughness are the lowest in 5Mo alloy, with values of 867 MPa, 7.3%, and 56 MPa·m1/2, respectively. However, it reaches its maximum in 6Mo alloy, where the strength, plasticity, and toughness increase to 984 MPa, 12.8%, and 74 MPa·m1/2, respectively. The mechanical properties of Ti-xMo-4Al-4Zr-3Nb-2Cr-1Fe alloys are affected mainly by solid-solution strengthening of Mo element, refinement of β grain, and changes in α/β phase content. This study lays a certain theoretical foundation for the theoretical research and composition development of new ultra-high strength and toughness titanium alloys.

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China Foundry2026

Creep behavior and fracture mechanism of high Al/Nb-containing TiAl alloy

Authors: Yan Wang, Qi Wang, Rui-run Chen, Yan-qing Su, Heng-zhi Fu

High Al content inhibits the formation of B2 phase, which improves creep resistance in high Al/Nb-containing TiAl alloys. In this work, the microstructure evolution and creep behavior of TiAl based alloy Ti-46Al-8Nb (at.%) with a high Al/Nb content, produced by the vacuum consumable electrode melting technology and the electromagnetic cold crucible melting technology, were studied. The microstructure of the Ti-46Al-8Nb alloy is composed of α2/γ phases arranged in layers with different orientations, which possesses smooth grain boundaries due to small-blocky segregation and irregular serrated grain boundaries caused by large-blocky segregation. Under conditions of 780-820 °C and 125-175 MPa for 200 h, it exhibits typical power-law creep characteristics. The apparent activation energy of creep (Q) and apparent stress exponent (n) of the Ti-46Al-8Nb alloy are Q=274 kJ·mol-1 and n=1.97, respectively. The creep deformation mechanism is grain boundary sliding. Cracks easily form at the smooth boundary. The irregular serrated boundaries with small specific surface area hinder the dislocation movement, thereby improving the boundary creep resistance. When the stress concentration reaches a certain degree, the cracks will initiate between the lamellar structures within the grain. The crack usually propagates along the boundary perpendicular to or at an angle of 45° with the stress axis until creep failure occurs.

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China Foundry2026

Effect of Ta addition on microstructure and mechanical properties of Ti46Al1.5Cr8Nb alloy

Authors: Jiang-shan Liang, Liao Mi, Hong-ze Fang, Xin Ding, Xian-fei Ding, Bao-hui Zhu, Rui-run Chen

The microstructure of high Nb-TiAl alloys was optimized by the addition of a small amount of Ta elements to further improve their properties. A series of Ti46Al1.5Cr8Nb-xTa (x=0.2, 0.4, 0.6, 0.8, 1.0, at.%) alloys were prepared by vacuum arc melting. The microstructure, mechanical properties, and related influencing mechanisms were systematically investigated. The results indicate that the solidification microstructure of the Ti46Al1.5Cr8Nb-xTa alloys comprises the γ-TiAl phase, α2-Ti3Al phase, and B2 phase. As the Ta content increases from 0.2at.% to 1.0at.%, the content of α2 phase and B2 phase increases, while the γ phase content decreases. Among them, the B2 phase shows the most pronounced change, being significantly refined, with its content increasing from 12.49% to 21.91%. In addition, the average size of the lamellar colony decreases from 160.65 to 94.44 μm. The addition of the Ta element shifts the solidification path toward lower aluminum concentrations, leading to changes in phase content. The tantalum-induced increase in the B2 phase and enhanced supercooling at the solidification front provide the basis for lamellar colony refinement. Compressive testing at room temperature reveals that the Ti46Al1.5Cr8Nb0.4Ta alloy exhibits optimal compressive properties, achieving a compressive strength of 2,434 MPa and a compressive strain of 33.1%. The improvement of its properties is attributed to a combination of lamellar colony refinement, solid solution strengthening resulting from the incorporation of Ta element, and a reduction in the c/a of the γ phase.

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Nano-Micro Letters2026

Crystallographic Engineering Enables Fast Low-Temperature Ion Transport of TiNb2O7 for Cold-Region Lithium-Ion Batteries

Authors: Lihua Wei, Shenglu Geng, Hailu Liu, Liang Deng, Yiyang Mao, Yanbin Ning, Biqiong Wang, Yueping Xiong, Yan Zhang, Shuaifeng Lou

TiNb2O7 represents an up-and-coming anode material for fast-charging lithium-ion batteries, but its practicalities are severely impeded by slow transfer rates of ionic and electronic especially at the low-temperature conditions. Herein, we introduce crystallographic engineering to enhance structure stability and promote Li+ diffusion kinetics of TiNb2O7 (TNO). The density functional theory computation reveals that Ti4+ is replaced by Sb5+ and Nb5+ in crystal lattices, which can reduce the Li+ diffusion impediment and improve electronic conductivity. Synchrotron radiation X-ray 3D nano-computed tomography and in situ X-ray diffraction measurement confirm the introduction of Sb/Nb alleviates volume expansion during lithiation and delithiation processes, contributing to enhancing structure stability. Extended X-ray absorption fine structure spectra results verify that crystallographic engineering also increases short Nb-O bond length in TNO-Sb/Nb. Accordingly, the TNO-Sb/Nb anode delivers an outstanding capacity retention rate of 89.8% at 10 C after 700 cycles and excellent rate performance (140.4 mAh g−1 at 20 C). Even at −30 °C, TNO-Sb/Nb anode delivers a capacity of 102.6 mAh g−1 with little capacity degeneration for 500 cycles. This work provides guidance for the design of fast-charging batteries at low-temperature condition.

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New Carbon Materials (新型炭材料)2025

A review of nanodiamond-based photocatalysts for solar energy conversion

Authors: ZHANG Wan, CHENG Xiangxiang, GUO Kesheng, ZHANG Hansong, LI Lanxiao, ZHAO Yongbing, ZHU Jiaqi, WANG Yongjie

Photocatalysis is an important technology for using solar energy to produce hydrogen, convert CO2 to synthetic fuels, and decrease persistent pollutant. However, conventional photocatalysts have limitations, including poor spectral absorption, inefficient charge separation, and structural instability under operational stress, which demand innovative durable materials with tailored electronic properties. Nanodiamond (ND) has recently been recognized as a suitable material because of its exceptional chemical stability, superior charge carrier mobility, and possible surface functionalization. While its intrinsic wide bandgap limits its response to visible-light, different methods have been demonstrated to activate its catalytic potential. Here, several emerging strategies for improving the catalytic performance of ND-based photocatalytic systems are summarized, including surface functionalization, plasmonic hybridization, heteroatom doping, and heterostructure design. And the structure-activity relationship and design principle are proposed to improve the light harvesting, charge transport, and redox kinetics for constructing high efficiency ND-based photocatalysts used in the renewable energy and environmental industries.

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Atomic Energy Science and Technology (原子能科学技术)2025

Radiation-hardened Pipeline in Microcontroller Core

Authors: XUE Haiwei, LI Xinqiang, WANG Jinxiang, FU Fangfa

With its growth in spacecraft control applications, the microcontroller (MCU) becomes increasingly sensitive to radiation and the risks of system failure. In a radiation environment, the MCU is vulnerable to impacts from high-energy particles, which can lead to single-event effect (SEE) that disrupt normal system operations. The pipeline of MCU, being the core structure of the system, is particularly susceptible to single-event upset (SEU) and potentially causes execution failures. However, existing radiation-hardening techniques offer limited effectiveness for pipelines. To enhance SEU resistance, this study focused on a 32-bit MCU core with eight pipeline stages, proposing a pipeline hardening approach that utilizes lockstep technology to improve fault tolerance. Signals from two processors were compared including register write data, register contents and pre-fetched instructions. Any discrepancies triggered error flags to indicate faults. When an error flag was raised, recovery was initiated through an interrupt. The interrupt handler then retrieved state information from the advanced peripheral bus (APB) slave module to restore the CPU’s operational state and resume execution. By combining hardware-based state preservation with software-driven error recovery, the proposed solution demonstrated significant improvements in fault tolerance rates and performance compared to traditional checkpoint-based techniques. After completing the pipeline hardening design, a fault injection platform was utilized in this paper to simulate real-world error conditions on internal processor modules. The platform was developed based on the circuit’s register-transfer-level (RTL) design and statistical results. The fault injection platform was performed by automatically finding all registers within the target design. The register values were forced to upset at the tens of nanoseconds scale in the RTL description of the circuit’s design. After running the circuit’s functional simulation, the statistics of the faults in registers were displayed on the platform, which evaluated the influence of SEU. The vulnerability of SEU in the circuit could be observed from the results of the soft error statistics. The post-hardening soft error rates were then measured and compared to pre-hardening data, providing a quantitative evaluation of the improvements. Using this method, the soft error rates of the modules in the MCU core such as PFU, DPU, and Cache AXIM are 40.07%, 26.36%, and 27.29% respectively before hardening. The soft error rates of modules mentioned above are reduced to 0%, 0.69%, and 1.11% after hardening. The hardened and non-hardened designs of the entire core were implemented in FPGA. The total resource utilization of the triple mode redundancy (TMR) is 111 984, as indicated by the number of look-up tables (LUTs) and registers consumed in the FPGA. The total resource utilization of this work is 78 034, and the ratio of resource utilization between this work and TMR is approximately 69.68%. The error recovery time for the hardened MCU processor was analyzed using the completion cycles of a bubble sort algorithm as a benchmark. In this paper, the average recovery cycle using the software checkpoint roll-back method is 36 479.06, and the average recovery cycle using this work is 26 922.5. The ratio of recovery cycles between this work and checkpoint roll-back is about 73.8%. Assessments through random fault injection and FPGA implementation indicate that this approach effectively reduces processor faults caused by soft errors while optimizing resource utilization and efficiency over triple-modular redundancy.

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Transactions of Nonferrous Metals Society of China (中国有色金属学报)2025

Achieving outstanding strength−ductility matching in dual-phase high-entropy alloys via modulation of BCC phase

Authors: Xu YANG, De-zhi CHEN, Li FENG, Gang QIN, Qi WANG, Rui-run CHEN

The impact of Mo on the microstructure, phase constitution, and tensile properties of Al1.25CoCrFeNi3−xMox (x=0.05, 0.1, 0.2, 0.3, and 0.5) high-entropy alloys (HEAs) was explored systematically through phase diagram simulation and experimental validation. The findings indicate that Mo addition transforms the microstructure from eutectic to hypereutectic and eventually to dendritic. Mo promotes the nucleation of the body-centered cubic phase by reducing the nucleation barrier and altering the valence electron concentration. As Mo content increases, yield strength rises, while the tensile strength and plasticity increase first and then decrease. Notably, the Al1.25CoCrFeNi2.8Mo0.2 HEA achieves an impressive tensile strength of 1234.80 MPa and a fracture strain of 19.33%. Key strengthening mechanisms include solid solution strengthening, grain boundary strengthening, and heterogeneous interface strengthening.

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China Foundry2025

Lightweight Al-Nb-Ti-V-Cr high entropy alloys with high hardness and enhanced mechanical properties via doping Co

Authors: Fang-dong Xu, De-zhi Chen, Rui-run Chen, Bin Gan, Jing-yue Yu

To develop high-hardness and high-strength lightweight high entropy alloys (LHEAs), a series of CoxAlNbTiVCr alloys were designed. The phase constitution, distribution, and crystal structure of the Laves phase in alloys can be altered by adjusting the composition of HEAs, which in turn influences their mechanical properties. CoxAlNbTiVCr (x=0, 0.5, 1, 1.5, and 2, atomic ratio percentage) LHEAs were designed and prepared to characterize the microstructure and tailor the mechanical properties. The introduction of Co changes the microstructure of LHEAs from a single B2 structure to a mixture dendrite structure, which consists of B2 phase, C14 and C15 Laves phase. Wherein the C14 and C15 Laves phases exhibit coupled growth. Several parameters including mixing enthalpy (ΔHmix), valence electron concentration (VEC), atomic radius size (δ), mixing entropy (ΔS), and electronegativity difference (Δχ) are used to predict the formation of B2 and Laves phase in LHEAs. When the Co content increases from 0 to 1.5at.%, Laves phase volume fraction gradually increases, which leads to an enhancement in the compressive strength from 1,520.8 MPa to 1,844.4 MPa. Co1.5AlNbTiVCr alloy exhibits the maximum Vickers hardness of 699.4 HV. The improvement of mechanical properties mainly originates from solid solution strengthening and second phase strengthening.

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Nano-Micro Letters2025

From Coils to Crawls: A Snake-Inspired Soft Robot for Multimodal Locomotion and Grasping

Authors: He Chen, Zhong Chen, Zonglin Liu, Jinhua Xiong, Qian Yan, Teng Fei, Xu Zhao, Fuhua Xue, Haowen Zheng, Huanxin Lian, Yunxiang Chen, Liangliang Xu, Qingyu Peng, Xiaodong He

Currently, numerous biomimetic robots inspired by natural biological systems have been developed. However, creating soft robots with versatile locomotion modes remains a significant challenge. Snakes, as invertebrate reptiles, exhibit diverse and powerful locomotion abilities, including prey constriction, sidewinding, accordion locomotion, and winding climbing, making them a focus of robotics research. In this study, we present a snake-inspired soft robot with an initial coiling structure, fabricated using MXene-cellulose nanofiber ink printed on pre-expanded polyethylene film through direct ink writing technology. The controllable fabrication of initial coiling structure soft robot (ICSBot) has been achieved through theoretical calculations and finite element analysis to predict and analyze the initial structure of ICSBot, and programmable ICSBot has been designed and fabricated. This robot functions as a coiling gripper capable of grasping objects with complex shapes under near infrared light stimulation. Additionally, it demonstrates multi-modal crawling locomotion in various environments, including confined spaces, unstructured terrains, and both inside and outside tubes. These results offer a novel strategy for designing and fabricating coiling-structured soft robots and highlight their potential applications in smart and multifunctional robotics.

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Nano-Micro Letters2025

Breaking Solvation Dominance Effect Enabled by Ion–Dipole Interaction Toward Long-Spanlife Silicon Oxide Anodes in Lithium-Ion Batteries

Authors: Shengwei Dong, Lingfeng Shi, Shenglu Geng, Yanbin Ning, Cong Kang, Yan Zhang, Ziwei Liu, Jiaming Zhu, Zhuomin Qiang, Lin Zhou, Geping Yin, Dalong Li, Tiansheng Mu, Shuaifeng Lou

Micrometer-sized silicon oxide (SiO) anodes encounter challenges in large-scale applications due to significant volume expansion during the alloy/de-alloy process. Herein, an innovative deep eutectic electrolyte derived from succinonitrile is introduced to enhance the cycling stability of SiO anodes. Density functional theory calculations validate a robust ion–dipole interaction between lithium ions (Li+) and succinonitrile (SN). The cosolvent fluoroethylene carbonate (FEC) optimizes the Li+ solvation structure in the SN-based electrolyte with its weakly solvating ability. Molecular dynamics simulations investigate the regulating mechanism of ion–dipole and cation–anion interaction. The unique Li+ solvation structure, enriched with FEC and TFSI−, facilitates the formation of an inorganic–organic composite solid electrolyte interphase on SiO anodes. Micro-CT further detects the inhibiting effect on the SiO volume expansion. As a result, the SiO|LiCoO2 full cells exhibit excellent electrochemical performance in deep eutectic-based electrolytes. This work presents an effective strategy for extending the cycle life of SiO anodes by designing a new SN-based deep eutectic electrolyte.

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Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)2025

Advances in micro/nanoparticle-enhanced Sn-based composite solders

Authors: Kaiming Liang, Wenqiang Wan, Yifei Li, Xin Zhang, Xiangdong Ding, Peng He, Shuye Zhang

Sn-based solder is a widely used interconnection material in the field of electronic packaging; however, the performance requirements for these solders are becoming increasingly demanding owing to the rapid development in this area. In recent years, the addition of micro/nanoreinforcement phases to Sn-based solders has provided a solution to improve the intrinsic properties of the solders. This paper reviews the progress in Sn-based micro/nanoreinforced composite solders over the past decade. The types of reinforcement particles, preparation methods of the composite solders, and strengthening effects on the microstructure, wettability, melting point, mechanical properties, and corrosion resistance under different particle-addition levels are discussed and summarized. The mechanisms of performance enhancement are summarized based on material-strengthening effects such as grain refinement and second-phase dispersion strengthening. In addition, we discuss the current shortcomings of such composite solders and possible future improvements, thereby establishing a theoretical foundation for the future development of Sn-based solders.

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Nano-Micro Letters2025

Advancements and Challenges in Organic–Inorganic Composite Solid Electrolytes for All-Solid-State Lithium Batteries

Authors: Xueyan Zhang, Shichao Cheng, Chuankai Fu, Geping Yin, Liguang Wang, Yongmin Wu, Hua Huo

To address the limitations of contemporary lithium-ion batteries, particularly their low energy density and safety concerns, all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming alternative. Among the various SEs, organic–inorganic composite solid electrolytes (OICSEs) that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale applications. However, OICSEs still face many challenges in practical applications, such as low ionic conductivity and poor interfacial stability, which severely limit their applications. This review provides a comprehensive overview of recent research advancements in OICSEs. Specifically, the influence of inorganic fillers on the main functional parameters of OICSEs, including ionic conductivity, Li+ transfer number, mechanical strength, electrochemical stability, electronic conductivity, and thermal stability are systematically discussed. The lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic perspective. Besides, the classic inorganic filler types, including both inert and active fillers, are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of OICSEs. Finally, the advanced characterization techniques relevant to OICSEs are summarized, and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs.

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Chinese Journal of Mechanical Engineering2025

Simulation Analysis of How Scratches Influence Frequency Splitting and Energy Dissipation of Hemispherical Resonator

Authors: Jingyang Guo, Henan Liu, Mingjun Chen, Jian Cheng

The fused quartz hemispherical resonator is the core component of the hemispherical resonator gyroscope. It features a complex shape and is made from a material that is difficult to process. Scratches are easily introduced during grinding, potentially degrading the mass-stiffness-damping symmetry; however, the underlying mechanisms of this influence have not been fully understood. This paper aims to investigate the effects of scratch defects on the frequency splitting and quality factor of the hemispherical resonator. First, finite element models of the hemispherical resonator with scratches are established. Then, the effects of the mass-stiffness factor, as well as the latitude and length of the scratches, on frequency splitting are analyzed. Furthermore, the impacts of latitude, length, and the first four harmonics of the unbalanced mass caused by scratches on thermoelastic damping and anchor loss are examined. Simulation results indicate that scratches above 55° latitude cause frequency splitting solely due to stiffness changes. Frequency splitting caused by scratches of the same size on the inherent rigidity shaft at the rim is approximately 50% of that near the transition fillet. Frequency splitting varies linearly with the volume of material removed by scratches. Scratches have little effect on thermoelastic damping. The first three harmonics of the unbalanced mass due to scratches at the rim are the primary contributors to anchor loss. Finally, focused ion beam trimming experiments are conducted at different locations on the hemispherical resonator. The trends observed in the experimental results are consistent with the simulation results. This work provides guidance for evaluating the impact of scratches on the performance of hemispherical resonators and for developing appropriate trimming processes.

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Chinese Journal of Mechanical Engineering2025

Thick-Panel Origami-Inspired Multiple Metamorphic Mechanisms with Planar-Spherical-Bennett Bifurcated Cycle

Authors: Yuyao Chen, Xi Kang, Bing Li

The intricate relationship between origami and mechanism underscores the fertile ground for innovation, which is particularly evident in the construction theory of thick-panel origami. Despite its potential, thick panel origami remains relatively unexplored in the context of single-loop metamorphic mechanisms. Drawing inspiration from thick-panel origami, particularly Miura origami, this study proposes a pioneering single-loop 6R multiple metamorphic mechanism. Through rigorous mathematical modeling (including the construction and resolution of the D-H closed-loop equation) and leveraging advanced analytical tools such as the screw theory and Lie theory, this study meticulously elucidates the planar, spherical, and Bennett motion branches of the mechanism. Furthermore, it delineates all the three bifurcation points between the motion branches, thereby providing a comprehensive understanding of the kinematic behavior of the mechanism. A metamorphic network can be constructed by applying several single-loop mechanisms to a symmetrical layout. Owing to its metamorphic properties, this network can act as a structural backbone for deployable antennas, aerospace shelters, and morphing wing units, thereby enabling a single mechanism to achieve multiple folding configurations. This paper not only introduces innovative metamorphic mechanisms but also suggests a promising method for uncovering and designing metamorphic mechanisms by developing new mechanisms from thick-panel origami.

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Chinese Journal of Mechanical Engineering2025

Understanding the Machining Process of Hierarchical Micro/Nanograting Structures Used for Optical Variable Device

Authors: Yanquan Geng, Wenhan Zhu, Xiaosong Zhang, Aoxiang Zhang, Yongda Yan, Hailong Cui, Bo Xue, Jiqiang Wang

Hierarchical micro/nanograting structures have attracted increasing attention owing to their significant applications in the fields of structural coloring, anti-counterfeiting, and decoration. Thus, the fabrication of hierarchical micro/nanograting structures is important for these applications. In this study, a strategy for machining hierarchical micro/nanograting structures is developed by controlling the tool movement trajectory. A coupling Euler-Lagrange finite element model is established to simulate the machining process. The effect of the machining methods on the nanograting formation is demonstrated, and a suitable machining method for reducing the cutting force is obtained. The height of the nanograting decreases with an increase in the tool edge radius. Furthermore, optical variable devices (OVDs) are machined using an array overlap machining approach. Coding schemes for the parallel column unit crossover and column unit in the groove crossover are designed to achieve high-quality machining of OVDs. The coloring of the logo of the Harbin Institute of Technology and the logo of the centennial anniversary of the Harbin Institute of Technology on the surface of metal samples, such as aluminum alloys, is realized. The findings of this study provide a method for the fabrication of hierarchical micro/nanograting structures that can be used to prepare OVDs.

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Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)2025

Two new amino acid derivatives as green corrosion inhibitors against Q235 steel in HCl solution: Experimental and theoretical investigations

Authors: Chaoyi Li, Minghao Su, Tianyi Hou, Yuhe Shi, Junrong Huang, Jing Qing, Wenxin Niu, Yinghe Zhang, Ling Zhang, Hengzhi You

Amino acids have emerged as promising green alternatives to replace toxic inhibitors in corrosion protection applications. In this study, we present a one-step synthetic approach to get 4-(tert-butyl)benzoyl)methionine (P-Meth) and 4-(tert-butyl)benzoyl)cysteine (P-Cys) through the acylation reactions between methionine or cysteine and p-tert-butylbenzoic acid, respectively, which exhibit a super protective performance toward metals against corrosion. The corrosion rates of Q235 steel in 1 M HCl were reduced from 4.542 to 0.202 and 0.312 mg·h−1·cm−2 in the presence of 100 mg·L−1 P-Meth and P-Cys, respectively. The surface structures of Q235 steel remained unbroken after 12 h in 1 M HCl medium. The charge transfer resistances of corrosion reactions were enhanced by 12 and 9 times in the presence of P-Meth and P-Cys, respectively. P-Meth and P-Cys were adsorbed onto the Q235 steel via chemical actions, which were accompanied by minimal physical action. Molecular dynamic simulations demonstrate the higher binding energy of P-Meth onto Q235 steel than P-Cys. The study contributes to the corrosion protection of metals with green and environmentally friendly methods.

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Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)2025

Evolution of the microstructure and mechanical properties of WE43 magnesium alloy during multipass hot rolling

Authors: Jianlei Yang, Yuxiang Zhai, Taotao Kang, Minmin Fu, Songhui Wang, Xintong Liu, Shijie Zhou, Wenzhuo Xie, Wenke Wang, Xinhua Liu

The evolution of the microstructure and mechanical properties of WE43 magnesium alloy during multipass hot rolling was investigated. Results revealed that multipass hot rolling promoted the formation of small second phases, which was conducive to multiple dynamic recrystallization, consequently improving the microstructure homogeneity and refining the average grain size from 34.3 μm in the initial material to 8.83 μm. Meanwhile, the rolling deformation rotated abundant c-axis of the grains in the normal direction, resulting in a strong fiber texture. The yield strength in the rolling direction (RD) was improved from 164 MPa in the initial material to 324 MPa in the Pass 3 sheet due to fine-grained strengthening, second-phase strengthening, and texture modification. In addition, the distribution maps of the deformation mechanism indicated that the yield strength anisotropy between the RD and the transverse direction (TD) can be attributed to the effects of the texture component on the dominant mechanism. The dominant deformation mechanism during the tensile test was the prismatic slip caused by the strong basal texture of the RD, whereas it had a lesser proportion of prismatic slip under the influence of the weak basal texture of the TD. Compared to the basal slip, the higher critical resolved shear stress of the prismatic slip resulted in a higher increase in yield strength along the RD at approximately 51 MPa than that along the TD (RD: increase of 160 MPa; TD: increase of 109 MPa).

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Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)2025

Zincophilic Cu/flexible polymer heterogeneous interfaces ensuring the stability of zinc metal anodes

Authors: Luyang Sun, Wenjia Zhang, Qiongqiong Lu, Pengfei Yue, Guoshang Zhang, Kexing Song, Yanqing Su

Aqueous zinc-ion batteries are regarded as promising electrochemical energy-storage systems for various applications because of their high safety, low costs, and high capacities. However, dendrite formation and side reactions during zinc plating or stripping greatly reduce the capacity and cycle life of a battery and subsequently limit its practical application. To address these issues, we modified the surface of a zinc anode with a functional bilayer composed of zincophilic Cu and flexible polymer layers. The zincophilic Cu interfacial layer was prepared through CuSO4 solution pretreatment to serve as a nucleation site to facilitate uniform Zn deposition. Meanwhile, the polymer layer was coated onto the Cu interface layer to serve as a protective layer that would prevent side reactions between zinc and electrolytes. Benefiting from the synergistic effect of the zincophilic Cu and protective polymer layers, the symmetric battery exhibits an impressive cycle life, lasting over 2900 h at a current density of 1 mA·cm−2 with a capacity of 1 mA·h·cm−2. Moreover, a full battery paired with a vanadium oxide cathode achieves a remarkable capacity retention of 72% even after 500 cycles.

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