Transactions of Nonferrous Metals Society of China (中国有色金属学报)•2026•DOI: 10.1016/S1003-6326(26)67069-0
The redox smelting of zinc leaching residue (ZLR) was investigated to determine the migration behavior and toxicity characteristics of zinc under varying anthracite addition, temperature, and holding time. The ZLR, containing 10–20 wt.% Zn, 0.5–5 wt.% Pb, and 0.1–0.5 wt.% Cd, generates TCLP leachate concentrations of Zn up to 4589.0 mg/L, far exceeding regulatory limits. Experimental results reveal that CaSO4 in the residue promotes the transformation of ZnFe2O4 into a ZnS–FeS eutectic, which hinders zinc recovery and elevates environmental risk due to its lower thermodynamic stability relative to (Fe,Zn)2SiO4, ZnFe2O4, and (ZnO)slag. At temperatures above 1573 K, the ZnS–FeS eutectic is oxidized by O2/(O)slag to ZnO(s), subsequently dissolved into the slag as chemically dissolved Zn, and finally reduced to Zn(g) by CO. Pre-desulfurization or increased oxygen potential enhances zinc volatilization. Under optimized conditions, the zinc recovery ratio reached 99.13%, and the residual zinc content in the slag decreased to 0.22 wt.%, substantially below the industrial range of 1.0–3.0 wt.%. A novel strategy integrating desulfurization pretreatment with redox smelting is proposed, which lowers the required smelting temperature and improves zinc recovery efficiency, offering a more economical and environmentally sustainable solution for ZLR treatment.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2026•DOI: 10.1088/1674-4926/25060033
The von Neumann architecture's physical separation of processing and memory imposes data transfer overhead exceeding 50% of total power consumption and latency penalties above 70%, driving compute-in-memory (CIM) adoption. This study optimizes a 55 nm 'L'-shaped split-gate floating-gate (FG) memory for CIM, fabricated on a commercial CMOS platform and evaluated via wafer acceptance test, Sentaurus TCAD simulation, and the DNN+NeuroSim V2.0 framework. Among devices with varying FG lengths, the 95-nm FG variant achieves a 5.35 V memory window, 19.7 μS maximum conductance under a varying voltage and width pulse scheme (VWPS), 32-state multi-level storage, and 92% training accuracy on CIFAR-10 using the VGG8 network. The split-gate structure suppresses over-erasure and enables low-power program/erase, while the non-series channel accelerates read operations. The optimization methodology, combining TCAD-guided design with experimental validation, provides a generalizable framework for determining optimal dimensions in other technology nodes. These results establish floating-gate engineering as a viable path for high-density, low-power analog synaptic arrays in CIM systems.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01984-x
The lack of macro-continuity and mechanical strength of covalent organic frameworks (COFs) has significantly limited their practical applications. Here, we propose an “alcohol-triggered defect cleavage” strategy to precisely regulate the growth and stacking of COF grains through a moderate reversed Schiff base reaction, realizing the direct synthesis of COF nanofibers (CNFs) with high aspect ratio (L/D = 103.05) and long length (> 20 μm). An individual CNF exhibits a biomimetic scale-like architecture, achieving superior flexibility and fatigue resistance under dynamic bending via a multiscale stress dissipation mechanism. Taking advantages of these structural features, we engineer CNF aerogels (CNF-As) with programmable porous structures (e.g., honeycomb, lamellar, isotropic) via directional ice-template methodology. CNF-As demonstrate 100% COF content, high specific surface area (396.15 m2 g−1) and superelasticity (~0% elastic deformation after 500 compression cycles at 50% strain), outperforming most COF-based counterparts. Compared with the conventional COF aerogels, the unique structural features of CNF-A enable it to perform outstandingly in uranium extraction, with an 11.72-fold increment in adsorption capacity (920.12 mg g−1) and adsorption rate (89.9%), and a 2.48-fold improvement in selectivity (U/V = 2.31). This study provides a direct strategy for the development of next-generation COF materials with outstanding functionality and structural robustness.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01749-6
Advances in wearable electronics and information technology drive sports data collection and analysis toward real-time visualization and precision. The growing pursuit of athleticism and healthy life makes it appealing for individuals to track their real-time health and exercise data seamlessly. While numerous devices enable sports and health monitoring, maintaining comfort over long periods remains a considerable challenge, especially in high-intensity and sweaty sports scenarios. Textiles, with their breathability, deformability, and moisture-wicking abilities, ensure exceptional comfort during prolonged wear, making them ideal for wearable platforms. This review summarized the progress of research on textile-based sports monitoring devices. First, the design principles and fabrication methods of smart textiles were introduced systematically. Textiles undergo a distinctive fiber–yarn–fabric or fiber–fabric manufacturing process that allows for the regulation of performance and the integration of functional elements at every step. Then, the performance requirements for precise sports data collection of smart textiles, including main vital signs, joint movement, and data transmission, were discussed. Lastly, the applications of smart textiles in various sports scenarios are demonstrated. Additionally, the review provides an in-depth analysis of the emerging challenges, strategies, and opportunities for the research and development of sports-oriented smart textiles. Smart textiles not only maintain comfort and accuracy in sports, but also serve as inexpensive and efficient information-gathering terminals. Therefore, developing multifunctional, cost-effective textile-based systems for personalized sports and healthcare is a pressing need for the future of intelligent sports.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01716-1
Current protective clothing often lacks sufficient comfort to ensure efficient performance of healthcare workers. Developing protective textiles with high air and moisture permeability is a potential and effective solution to discomfort of medical protective clothing. However, realizing the facile production of a protective textile that combines safety and comfort remains a challenge. Herein, we report the fabrication of highly permeable protective textiles (HPPT) with micro/nano-networks, using non-solvent induced phase separation synergistically driven by CaCl2 and fluorinated polyurethane, combined with spraying technique. The HPPT demonstrates excellent liquid repellency and comfort, ensuring high safety and a dry microenvironment for the wearer. The textile exhibits not only a high hydrostatic pressure (12.86 kPa) due to its tailored small mean pore size (1.03 μm) and chemical composition, but also demonstrates excellent air permeability (14.24 mm s−1) and moisture permeability (7.92 kg m−2 d−1) owing to the rational combination of small pore size and high porosity (69%). The HPPT offers superior comfort compared to the commercially available protective materials. Additionally, we elucidated a molding mechanism synergistically inducted by diffusion–dissolution-phase separation. This research provides an innovative perspective on enhancing the comfort of medical protective clothing and offers theoretical support for regulating of pore structure during phase separations.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01655-x
The past decade has witnessed the rapid increasement in power conversion efficiency of perovskite solar cells (PSCs). However, serious ion migration hampers their operational stability. Although dopants composed of varied cations and anions are introduced into perovskite to suppress ion migration, the impact of cations or anions is not individually explored, which hinders the evaluation of different cations and further application of doping strategy. Here we report that a special group of sulfonic anions (like CF3SO3−) successfully introduce alkaline earth ions (like Ca2+) into perovskite lattice compared to its halide counterparts. Furthermore, with effective crystallization regulation and defect passivation of sulfonic anions, perovskite with Ca(CF3SO3)2 shows reduced PbI2 residue and metallic Pb0 defects; thereby, corresponding PSCs show an enhanced PCE of 24.95%. Finally by comparing the properties of perovskite with Ca(CF3SO3)2 and FACF3SO3, we found that doped Ca2+ significantly suppressed halide migration with an activation energy of 1.246 eV which accounts for the improved operational stability of Ca(CF3SO3)2-doped PSCs, while no obvious impact of Ca2+ on trap density is observed. Combining the benefits of cations and anions, this study presents an effective method to decouple the effects of cations and anions and fabricate efficient and stable PSCs.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6117-x
The determination of discontinuity shear strength is an important concern in rock engineering. Previous research mainly focused on the shear behavior of discontinuities with identical joint wall compressive strengths (DIJCS). However, the shear behavior of discontinuities with different joint wall compressive strengths (DDJCS) and 3D surface morphology had been rarely reported. In this study, matched mortar DDJCSs were prepared using 3D printed photosensitive resin molds. Direct shear tests were carried out under three kinds of normal stress (ranging from 0.5 to 3.0 MPa) to analyze the shear strength and contact zones of DDJCS during shearing. The results show that the contact zones of DDJCS during shearing are scattered in the steep zones facing the shear direction. It is verified that Grasselli and Develi’s directional surface roughness characterization method can be used to predict the shear-induced potential contact zones of DDJCS. When the critical apparent dip angle is equal to the peak dilation angle, the predicted contact area agrees well with the actual contact area. A 3D directional roughness parameter with clear physical meaning was introduced to characterize discontinuity surface roughness. A 3D modified joint roughness coefficient-joint wall compressive strength (JRC-JCS) criterion that can both predict the shear strength of DDJCS and DIJCS was proposed based on the newly defined roughness parameter. The proposed criterion was validated by 77 direct shear tests presented by this study and 163 direct shear tests presented by other investigators. The results show that the proposed criterion was generally reliable for the peak shear strength prediction of DDJCS and DIJCS (within 16%). It is also found that the new criterion can capture the anisotropy of the peak shear strength of DDJCS. The anisotropy of DDJCS decreases with increasing normal stress. It should be noted that the anisotropy of the shear strength of DDJCS was not investigated experimentally, and further experiments should be conducted to verify it.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6085-1
Rock-like specimens containing a joint with different inclination angles and roughness were prepared using 3D printing technology. Then, true triaxial compression loading experiments were conducted on those jointed specimens. The increase in roughness leads to an increase in the axial strength and peak strain. With the increasing inclination angle, the axial strength initially decreases from 30° to 60° and then increases from 60° to 90°. While the peak strain first rises from 30° to 45° and then declines from 45° to 90°. The variation in failure mode results from differences in lateral stress on the joints under different strike directions. Specimens with joint strike parallel to the intermediate principal stress predominantly showed matrix or matrix-joint mixed shear failure, whereas those parallel to the minimum principal stress exhibited matrix shear failure. The analysis results of acoustic emission signals indicate the crack number and shear crack percentage increase with the increasing roughness and first decrease (30° to 60°), then increase (60° to 90°) with the increasing inclination angle. The research results can provide some guidance for the design and support of underground engineering with jointed surrounding rock.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-024-2958-9
Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is crucial for developing rechargeable zinc–air batteries (ZABs). Herein, an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere (NCS) decorated with dual-phase Co/Co7Fe3 heterojunctions (CoFe@NCS). The phase composition of materials has been adjusted by controlling the alloying degree. The optimal CoFe0.08@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm−2 for OER in an alkaline electrolyte. The intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co7Fe3 alloy and metallic Co species. When the CoFe0.08@NCS material is used as air–cathode catalyst of rechargeable liquid-state zinc–air battery (ZAB), the device shows a high peak power-density (157 mW·cm−2) and maintains a stable voltage gap over 150 h, outperforming those of the benchmark (Pt/C+RuO2)-based device. In particular, the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending conditions. Our work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.