Nano Research•2026•DOI: 10.26599/NR.2026.94908790
The integration of electrothermal films into smart windows demands simultaneous high optical transparency and exceptional heating performance, a trade-off that has constrained flexible transparent heater development. This work reports a transparent conductive single-wall carbon nanotube (SWCNT) film composed of highly crystalline, long SWCNTs in small bundles, synthesized by floating catalyst chemical vapor deposition (FCCVD). The small-bundle SWCNT film, with an average bundle diameter of 7.1 nm, achieves a sheet resistance of 26 Ω/□ at 82% transmittance and reaches a stable temperature of 102 °C under a low applied voltage of 20 V. The superior electrothermal performance relative to large-bundle counterparts originates from a higher areal nanotube density and more efficient conductive pathways at equivalent transmittance. Integrating this transparent heating film with a paraffin wax/polydimethylsiloxane (PW/PDMS) thermochromic functional layer yields a large-area flexible smart window. The device exhibits a reversible visible light transmittance range from 0.17% to 78% and exceptional cycling stability. This study overcomes the transparency–conductivity trade-off in transparent electrothermal films, providing a viable route for flexible smart windows and related thermal management devices.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01956-1
Violet phosphorus, a recently explored layered elemental semiconductor, has attracted much attention due to its unique photo-electric, mechanical properties, and high hole mobility. Herein, violet arsenic phosphorus has for the first time been synthesized by a molten lead method. The crystal structure of violet arsenic phosphorus (P83.4As0.6, CSD-2408761) was determined by single crystal X-ray diffraction to have similar structure as that of violet phosphorus, where P12 is occupied by arsenic/phosphorus (As/P) atoms as mixed occupancy sites As1/P12. The arsenic substitution has been demonstrated to tune the band structure of violet phosphorus, switching p-type of violet phosphorus to high-performance n-type violet arsenic phosphorus. The effective electron mass along the <010> direction is significantly reduced from 1.792 to 0.515 m0 by arsenic substitution, resulting in an extremely high electron mobility of 2622.503 cm2 V⁻1 s⁻1. The field effect transistor built with P83.4As0.6 nanosheets was measured to have a high electron mobility (137.06 cm2 V⁻1 s⁻1, 61.2 nm), even under ambient conditions for 5 h, much higher than the hole mobility of violet phosphorene nanosheets (4.07 cm2 V⁻1 s⁻1, 73.3 nm). This work provides a new idea for designing phosphorus-based materials for field effect transistors, giving significant potential in complementary metal–oxide–semiconductor applications.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01733-0
Shuttle effect of polysulfides overshadows the superiorities of lithium–sulfur batteries. Size–sieving effect could address this thorny trouble rely on size differ in polysulfides and lithium ions. However, clogged polysulfides pose some challenges for cathode and are rarely recycled during charging/discharging. Herein, an amino functionalized titanium-organic framework is designed for modifying lithium–sulfur batteries separator to address the aforementioned challenges. Wherein, the introduction of amino narrows titanium–organic framework pore size, enabling functional separator to selectively modulate lithium ions and polysulfides migration using size-sieving effect, thereby completely suppressing polysulfides shuttle. Furthermore, the blocked polysulfides will be adsorbed on the separator surface by positively charged amino leveraging electrostatic adsorption, ensuring polysulfides to redistribute and reuse, and boosting active materials utilization. Significantly, the migration of lithium ions is not hindered since there are lithium ions transfer channels formed via Lewis acid–base interaction with the help of amino. Combined with these virtues, the lithium–sulfur batteries with amino functionalized titanium-organic framework modified separator enjoy an ultralow attenuation rate of 0.045% per cycle over 1000 cycles at 1.0C. Electrostatic adsorption and Lewis acid–base interaction cover deficiencies existing in the inhibition of polysulfides shuttle by size-sieving effect, providing fresh insight into the advancement of lithium-sulfur batteries.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01637-5
Building anion-derived solid electrolyte interphase (SEI) with enriched LiF is considered the most promising strategy to address inferior safety features and poor cyclability of lithium-metal batteries (LMBs). Herein, we discover that, instead of direct electron transfer from surface polar groups to bis(trifluoromethanesulfonyl)imide (TFSI−) for inducing a LiF-rich SEI, the dipole-induced fluorinated-anion decomposition reaction begins with the adsorption of Li ions and is highly dependent on their mobility on the polar surface. To demonstrate this, a single-layer graphdiyne on MXene (sGDY@MXene) heterostructure has been successfully fabricated and integrated into polypropylene separators. It is found that the adsorbed Li ions connect electron-donating sGDY@MXene to TFSI−, facilitating interfacial charge transfer for TFSI− decomposition. However, this does not capture the entire picture. The sGDY@MXene also renders the adsorbed Li ions with high mobility, enabling them to reach optimal reaction sites and expedite their coordination processes with O on O=S=O and F on the broken –CF3−, facilitating bond cleavage. In contrast, immobilized Li ions on the more lithiophilic pristine MXene retard these cleavage processes. Consequently, the decomposition reaction is accelerated on sGDY@MXene. This work highlights the dedicate balance between lithiophilicity and Li-ion mobility in effectively promoting a LiF-rich SEI for the long-term stability of LMBs.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2026-41-03-07)
Conventional lignin-based carbons typically have sluggish ion transport and a limited number of active sites, which restrict their performance as electrodes in supercapacitors. A Moiré-like morphology was engineered by the in-situ deposition of lignin carbon onto DVD matrix onto lignin carbon for the fabrication of a photo-assisted supercapacitor (PASC). The Moiré-like structure modulates light propagation across different frequencies by dispersion effects, thereby increasing surface light absorption and improving the electrochemical performance of the PASC. Under illumination, the carbon has a specific capacitance of 253.5 F g−1 at 0.5 A g−1, corresponding to a 35.6% improvement over one without this grating surface (186.9 F g−1). A symmetrical capacitor using this material has an areal capacitance of 58.84 mF cm−2 and an energy density of 4.46 Wh kg−1 at a power density of 365.2 W kg−1, maintaining 85.2% of its initial capacitance after 5000 cycles, thus demonstrating excellent cycling stability. This work suggests a cost-effective strategy to simultaneously improve the light-harvesting ability and capacitive performance of PASCs.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2025•DOI: 10.1088/1674-4926/25050007
Perovskite solar cells (PSCs) have emerged as a highly promising photovoltaic technology, achieving power conversion efficiencies exceeding 25%. However, stability remains a critical challenge due to degradation under heat, moisture, and operational stress. Fullerenes, particularly C60 and its derivative PCBM, have been widely used as electron-transport materials in PSCs, but they offer limited interfacial stabilization. Recent innovative approaches have focused on designing fullerene-based materials that not only facilitate electron conduction but also actively enhance and protect the perovskite interface for long-term stability. One approach involves a magnetic endohedral metallofullerene (Nd@C82) integrated into a polymer matrix (PMMA) to form a robust interface layer. This Nd@C82-PMMA layer simultaneously enhances electron extraction and provides in-situ encapsulation, achieving a remarkable power conversion efficiency of 26.78% (certified 26.29%) on small-area cells and 23.08% on a 16 cm2 module. Unencapsulated cells retained approximately 82% of their initial efficiency after 2500 h at 65°C and over 99% after 1000 h under damp-heat conditions. Another strategy involves chemically modifying C60 to create an ionic salt (CPMAC) that forms stronger electrostatic coupling with the perovskite, reducing interfacial defects and enhancing mechanical toughness. CPMAC-based cells achieved efficiencies up to ~26%, about 0.6% higher than pristine C60, and exhibited only one-third of the performance drop over 2000 h under thermal and humidity stress. These innovations demonstrate synergistic optimization of efficiency and durability in perovskite photovoltaics.
China Foundry•2025•DOI: 10.1007/s41230-025-4199-6
An Al2O3/Al-Cu-Mn composite was fabricated using a combination of ball milling and liquid-solid reaction, with a nominal composition of Al-4Cu-0.5Mn-2.8γ-Al2O3. The composite contains reinforcement particles, including nano-sized θ’ and T(Al20Cu2Mn3) particles after T6 heat treatment, as well as in-situ synthesized nano-sized γ-Al2O3 particles. Tensile tests of the Al-4Cu-0.5Mn-2.8γ-Al2O3 composite and the Al-4Cu-0.5Mn base alloy after T6 treatment were carried out at room temperature and elevated temperatures (200 °C, 300 °C, and 400 °C). Compared with the base alloy, the yield strength of the Al-4Cu-0.5Mn-2.8γ-Al2O3 composite after T6 treatment increases significantly from 187 MPa to 263 MPa at room temperature. Simultaneously, at elevated temperatures, the yield strength is also enhanced, with a yield strength of 52 MPa at 400 °C for this composite. The in-situ fabricated γ-Al2O3 particles, mainly distributed along the grain boundaries, are supposed to play the main strengthening role, especially at high temperatures. This work acts as a reference for designing composites for high-temperature applications.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-025-3121-y
This study explores a hydrogen-assisted mineral phase transformation process with synergistic desulfurization for the efficient recovery of iron from the high-pressure acid leach (HPAL) tailings of laterite nickel ore. HPAL tailings containing 51.50wt% iron and 2.09wt% sulfur present environmental challenges due to their sulfur content. Pre-treatment at 950°C for 15 min successfully reduced the sulfur content to 0.295wt% and increased the iron grade to 57.66wt%. Further hydrogen-assisted mineral phase transformation at 520°C for 30 min, using 40vol% hydrogen and a gas flow rate of 600 mL·min–1, resulted in a product with an iron grade of 61.00wt% and 90.11% iron recovery. The overall desulfurization rate reached 85.83% when wet scrubbing and limestone were used to capture the sulfur. This study demonstrates the efficiency of this hydrogen-assisted process for sustainable iron recovery and sulfur removal from laterite nickel ore tailings, with potential for industrial applications.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-025-3146-2
Supercapacitors (SCs) stand out among various energy storage devices owing to their high power density and long-term cycling stability. As new two-dimensional material, MXenes have become a research hotspot in recent years owing to their unique structure and rich surface functional groups. Compared with other materials, MXenes are more promising for SCs owing to their tunable precursors, structural stability, and excellent electrical conductivity. However, the rate performance and electrochemical reaction activity of MXene materials are poor, and stacking severely limits their application. Therefore, various modification strategies are employed to improve the electrochemical performance of MXene materials. As the modification strategy of MXene electrode materials often involves increasing the number of ion transport channels to expose more active sites, the packing density is also affected to different degrees. Therefore, achieving a balance between high volumetric capacitance and rapid ion transport has become a key issue for the application of MXene-based SCs in wearable devices and microdevices. In this paper, the latest progress in the preparation methods and modification strategies of MXenes in recent years is reviewed with the aim of achieving both high volumetric capacitance and high ion transport for expanding the application of MXene-based SCs in microdevices and wearable devices.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-025-3110-1
Real-time identification of rock strength and cuttability based on monitoring while cutting during excavation is essential for key procedures such as the precise adjustment of excavation parameters and the in-situ modification of hard rocks. This study proposes an intelligent approach for predicting rock strength and cuttability. A database comprising 132 data sets is established, containing cutting parameters (such as cutting depth and pick angle), cutting responses (such as specific energy and instantaneous cutting rate), and rock mechanical parameters collected from conical pick-cutting experiments. These parameters serve as input features for predicting the uniaxial compressive strength and tensile strength of rocks using regression fitting and machine learning methodologies. In addition, rock cuttability is classified using a combination of the analytic hierarchy process and fuzzy comprehensive evaluation method, and subsequently identified through machine learning approaches. Various models are compared to determine the optimal predictive and classification models. The results indicate that the optimal model for uniaxial compressive strength and tensile strength prediction is the genetic algorithm-optimized backpropagation neural network model, and the optimal model for rock cuttability classification is the radial basis neural network model.