Opto-Electronic Advances (光电进展)•2026•DOI: 10.29026/oea.2026.250150
This study presents the first demonstration of a fast step heterodyne light-induced thermoelastic spectroscopy (SH-LITES) sensor utilizing a high-frequency quartz tuning fork (QTF) with a resonant frequency of approximately 100 kHz. The theoretical basis of heterodyne LITES (H-LITES) signal generation is analyzed, and an acetylene (C2H2) H-LITES sensor is constructed to evaluate performance. Comparative experiments between the high-frequency QTF and a standard commercial QTF (resonant frequency ~32.768 kHz) reveal that the high-frequency QTF achieves a tenfold faster response time, with a measurement cycle of 33 ms—90% shorter than commercial counterparts. The proposed SH-LITES technique further reduces the scanning time to 15 ms, representing the shortest LITES measurement time reported to date. To validate dynamic gas detection capabilities, an H2O-LITES system integrating both QTF types is employed for real-time monitoring of H2O concentration during various respiration patterns. Results demonstrate that SH-LITES more accurately captures rapid H2O concentration fluctuations during respiration, outperforming the commercial QTF-based H-LITES sensor in fast-response scenarios. These findings establish a new benchmark for high-speed trace gas sensing with potential applications in combustion diagnostics, healthcare monitoring, and environmental surveillance.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2026•DOI: 10.1016/j.ijmst.2026.02.007
Addressing the scientific problem of unclear understanding of in-situ internal stress and its evolution in deep rock masses, a scientific definition and implementation path for the concept of in-situ internal stress consolidation-sealing in deep rock masses are proposed, and a set of in-situ internal stress consolidation-sealing test device for deep rock masses has been independently developed. The device consists of a material consolidation cultivation module, an in-situ internal stress environment simulation module, and a multi-source information capture module. And the three mechanical tests of internal stress preservation, internal stress release and conventional were carried out with the device. The evolution law of the deformation parameters in the internal stress consolidation-sealing stage was studied, and the difference characteristics of the deformation parameters before and after the internal stress releasing were compared and analyzed. The results show that the internal stress consolidation-sealing significantly affects the mechanical properties of the simulated rock material, while the internal stress release leads to the damage of the material properties, suggesting that the presence and influence of internal stress should not be overlooked. This study could provide a new research direction and scientific devices for the expansion and deepening of the field of deep in-situ rock mechanics.
Journal of Central South University•2026•DOI: 10.1007/s11771-026-6161-1
Zn-Mn alloys are regarded as promising biodegradable metals for orthopedic applications owing to their moderate degradation rates and favorable osteogenic properties. However, the presence of a substantial number of second-phase particles in Zn-based alloys might induce severe localized degradation via micro-coupling corrosion, thereby compromising the mechanical integrity of the alloy during in vivo tissue regeneration. In this study, high-pressure solid solution (HPSS) treatment was conducted at 5 GPa and 380 ℃ for 1 h to fabricate Zn-0.5Mn alloys. Microstructural characterization revealed that the HPSS treatment facilitated the formation of a supersaturated solid solution by completely dissolving the ζ-MnZn13 phase into the α-Zn matrix. The resultant strengthening mechanisms, including supersaturated solid solution strengthening, grain-size strengthening, and dislocation strengthening, collectively enhanced the compressive yield strength (σcys) of the Zn-0.5Mn alloy to about 183.7 MPa, approximately three times that of the as-cast (AC) Zn-0.5Mn alloy. Moreover, compared with the AC alloy, the HPSS Zn-0.5Mn alloy exhibited uniform degradation behavior with a markedly reduced degradation rate.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01993-w
With the escalating demand for safe, sustainable, and high-performance energy storage systems, hydrogel electrolytes have emerged as promising alternatives to conventional liquid electrolytes in zinc-ion batteries. By integrating the high ionic conductivity of liquid electrolytes with the mechanical robustness of solid frameworks, hydrogel electrolytes offer distinct advantages in suppressing zinc dendrite formation, enhancing interfacial stability, and enabling reliable operation under extreme environmental conditions. This review systematically summarizes the fundamental characteristics and design criteria of hydrogel electrolytes, including mechanical flexibility, ionic transport capabilities, and environmental adaptability. It further explores various compositional design strategies involving natural polymers, synthetic polymers, and composite systems, as well as the incorporation of electrolyte salts and functional additives. In addition, recent advances in functional optimization, such as anti-freezing properties, self-healing abilities, thermal responsiveness, and biocompatibility, are comprehensively discussed. Finally, the review outlines the current challenges and proposes potential directions for future research.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01851-9
Ambient-air, moisture-assisted annealing is widely used in fabricating perovskite solar cells (PSCs). However, the inherent sensitivity of perovskite intermediate-phase to moisture—due to fast and spontaneous intermolecular exchange reaction—requires strict control of ambient humidity and immediate thermal annealing treatment, raising manufacturing costs and causing fast nucleation of perovskite films. We report herein a self-buffered molecular migration strategy to slow down the intermolecular exchange reaction by introducing a n–butylammonium bromide shielding layer, which limits moisture diffusion into intermediate-phase film. This further endows the notably wide nucleation time and humidity windows for perovskite crystallization in ambient air. Consequently, the optimized 1.68 eV-bandgap n-i-p structured PSC reaches a record-high reverse-scan (RS) PCE of 22.09%. Furthermore, the versatility and applicability of as-proposed self-buffered molecular migration strategy are certified by employing various shielding materials and 1.53 eV-/1.77 eV-bandgap perovskite materials. The n-i-p structured PSCs based on 1.53 eV- and 1.77 eV-bandgap perovskite films achieve outstanding RS PCEs of 25.23% and 19.09%, respectively, both of which are beyond of the state-of-the-art ambient-air processed PSCs.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01790-5
Low ionic conductivity is a major obstacle for polymer solid-state electrolytes. In response to this issue, a design concept of enhanced regional electric potential difference (EREPD) is proposed to modulate the interaction of nanofillers with other components in the composite polymer solid-state electrolytes (CPSEs). While ensuring the periodic structure of the graphdiyne (GDY) backbone, methoxy-substituted GDY (OGDY) is prepared by an asymmetric substitution strategy, which increases the electric potential differences within each repeating unit of GDY. The staggered distributed electron-rich regions and electron-deficient regions on the two-dimensional plane of OGDY increase the free Li+ concentration through Lewis acid–base pair interaction. The adjacent ERRs and EDRs form uniformly distributed EREPDs, creating a continuous potential gradient that synergistically facilitates the efficient migration of Li+. Impressively, the OGDY/poly(ethylene oxide) (PEO) exhibits a high ionic conductivity (1.1 × 10−3 S cm−1) and ion mobility number (0.71). In addition, the accelerated Li+ migration promotes the formation of uniform and dense SEI layers and inhibits the growth of lithium dendrites. As a proof of concept, Li||Li symmetric cell and Li||LiFePO4 full cell and pouch cell assembled with OGDY/PEO exhibit good performance, highlighting the effectiveness of our EREPD design strategy for improving CPSEs performance.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01763-8
All-inorganic perovskite materials exhibit exceptional thermal stability and promising candidates for tandem devices, while their application is still in the initial stage. Here, a metal halide doping strategy was implemented to enhance device performance and stability for inverted CsPbI3 perovskite solar cells (PSCs), which are ideal for integration into perovskite/silicon tandem solar cells. The lanthanide compound terbium chloride (TbCl3) was employed to improve buried interface between [4-(3,6-Dimethyl-9H-carbazol-9-yl) butyl] phosphonic acid (Me-4PACz) and perovskite layer, thereby enhancing the crystallinity of CsPbI3 films and passivating non-radiative recombination defects. Thus, the inverted CsPbI3 PSCs achieved an efficiency of 18.68% and demonstrated excellent stability against water and oxygen. Meanwhile, remarkable efficiencies of 29.40% and 25.44% were, respectively, achieved in four-terminal (4T) and two-terminal (2T) perovskite/silicon mechanically tandem devices, which are higher efficiencies among reported all-inorganic perovskite-based tandem solar cells. This study presents a novel approach for fabricating highly efficient and stable inverted all-inorganic PSCs and perovskite/silicon tandem solar cells.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01708-1
Rapid development of artificial intelligence requires the implementation of hardware systems with bioinspired parallel information processing and presentation and energy efficiency. Electrolyte-gated organic transistors (EGOTs) offer significant advantages as neuromorphic devices due to their ultra-low operation voltages, minimal hardwired connectivity, and similar operation environment as electrophysiology. Meanwhile, ionic–electronic coupling and the relatively low elastic moduli of organic channel materials make EGOTs suitable for interfacing with biology. This review presents an overview of the device architectures based on organic electrochemical transistors and organic field-effect transistors. Furthermore, we review the requirements of low energy consumption and tunable synaptic plasticity of EGOTs in emulating biological synapses and how they are affected by the organic materials, electrolyte, architecture, and operation mechanism. In addition, we summarize the basic operation principle of biological sensory systems and the recent progress of EGOTs as a building block in artificial systems. Finally, the current challenges and future development of the organic neuromorphic devices are discussed.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01640-w
The large-scale use of ample marine energy will be one of the most important ways for human to achieve sustainable development through carbon neutral development plans. As a burgeoning technological method for electromechanical conversion, triboelectric nanogenerator (TENG) has significant advantages in marine energy for its low weight, cost-effectiveness, and high efficiency in low-frequency range. It can realize the efficient and economical harvesting of low-frequency blue energy by constructing the floating marine energy harvesting TENG. This paper firstly introduces the power transfer process and structural composition of TENG for marine energy harvesting in detail. In addition, the latest research works of TENG on marine energy harvesting in basic research and structural design are systematically reviewed by category. Finally, the advanced research progress in the power take-off types and engineering study of TENG with the marine energy are comprehensively generalized. Importantly, the challenges and problems faced by TENG in marine energy and in situ electrochemical application are summarized and the corresponding prospects and suggestions are proposed for the subsequent development direction and prospects to look forward to promoting the commercialization process of this field.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2024-39-04-07)
A toughener that can effectively improve the interlaminar toughness in carbon fiber composites is crucial for various applications. We investigated, the toughening effects of phenolphthalein-based cardo poly (ether sulfone) (PES-C) on E51/ DETDA epoxy and its carbon fiber composites (CFCs). Scanning electron microscopy showed that the phase structures of PES-C/epoxy blends change from island (of dispersed phase) structures to bi-continuous structures (of the matrix) as the PES-C content increased, which is associated with reaction-induced phase separation. After adding 15 phr PES-C, the glass transition temperature (Tg) of the blends increased by 51.5 °C, and the flexural strength, impact strength and fracture toughness of the blends were improved by 41.1%, 186.2% and 42.7%, respectively. These improvements could be attributed to the phase separation structure of the PES-C/epoxy system. A PES-C film was used to improve the mode-II fracture toughness (GIIC) of CFCs. The GIIC value of the 7 μm PES-C film toughened laminate was improved by 80.3% compared to that of the control laminate. The increase in GIIC was attributed to cohesive failure and plastic deformation in the interleaving region.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2024-39-02-09)
It is imperative to design suitable anode materials for both lithium-ion (LIBs) and sodium-ion batteries (SIBs) with a high-rate performance and ultralong cycling life. We fabricated a MoO2/MoS2 heterostructure that was then homogeneously distributed in N,S-doped carbon nanofibers (MoO2/MoS2@NSC) by electrospinning and sulfurization. The one-dimensional carbon fiber skeleton serves as a conductive frame to decrease the diffusion pathway of Li+/Na+, while the N/S doping creates abundant active sites and significantly improves the ion diffusion kinetics. Moreover, the deposition of MoS2 nanosheets on the MoO2 bulk phase produces an interface that enables fast Li+/Na+ transport, which is crucial for achieving high efficiency energy storage. Consequently, as the anode for LIBs, MoO2/MoS2@NSC gives an excellent cycling stability of 640 mAh g−1 for 2000 cycles under 5.0 A g−1 with an ultralow average capacity drop of 0.002% per cycle and an exceptional rate capability of 614 mAh g−1 at 10.0 A g−1. In SIBs, it also produces a significantly better electrochemical performance (reversible capacity of 242 mAh g−1 under 2.0 A g−1 for 2000 cycles and 261 mAh g−1 under 5.0 A g−1). This work shows how introducing a novel interface in the anode can produce rapid Li+/Na+ storage kinetics and a long cycling performance.
Journal of Semiconductors (半导体学报 - 中国科学院半导体研究所)•2025•DOI: 10.1088/1674-4926/25010026
AlGaN-based LEDs with peak wavelength below 240 nm (far-UVC) pose no significant harm to human health, thus highlighting their broader application potential. While, there is a significant Schottky barrier between the n-electrode and Al-rich n-AlGaN, adversely impeding electron injection and resulting in considerable heat generation. Here, we fabricate V-based electrodes of V/Al/Ti/Au on n-AlGaN with Al content over 80% and investigate the relationship between the metal diffusion and contact properties during the high-temperature annealing process. Experiments reveal that decreasing V thickness in the electrode promotes the diffusion of Al towards the surface of n-AlGaN, which facilitates the formation of VN and thus the increase of local electron concentration, resulting in lower specific contact resistivity. Then, increasing the Al thickness inhibits the diffusion of Au to the n-AlGaN surface, suppressing the rise of Schottky barrier. Experimentally, an optimized n-electrode of V(10 nm)/Al(240 nm)/Ti(40 nm)/Au(50 nm) on n-Al0.81Ga0.19N is obtained, realizing an optimal specific contact resistivity of 7.30 × 10−4 Ω·cm2. Based on the optimal n-electrode preparation scheme for Al-rich n-AlGaN, the work voltage of a far-UVC LED with peak wavelength of 233.5 nm is effectively reduced.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.06.009
Borehole pressure relief helps prevent rock bursts. However, this may change the physical and mechanical properties of the surrounding rock, affect the variation of the plastic zone of the roadway, and lead to the failure of roadway support, thus threatening the safety of the roadway. In this paper, the variable angle shear test of drilled specimens under the action of static and dynamic loads is used to study the evolution of mechanical parameters of the specimens and their influence on the plastic zone of the surrounding rock. The shear strength decreases linearly with the increase of drilling diameter. With the increase of pre-static load level and dynamic load amplitude, the cohesion first increases and then decreases, and the internal friction angle decreases. Moreover, the shear failure surface changes from rough to smooth. The reasons include that the static load enhances the tooth cutting effect and the repeated friction of cracks caused by the dynamic load. Borehole pressure relief leads to an increase in the radius of the plastic zone of the surrounding rock following a quadratic function. The research results of this paper provide a theoretical basis for designing drilling unloading parameters and supporting parameters for rock burst roadways.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6103-3
In deep underground engineering construction, the dominant rock failure mode, whether by tension or shear, influences the engineering instability. Therefore, the critical triggering conditions that induce shear or tensile fractures in rocks urgently need further investigation. This paper designs direct shear tests on intact limestone under different normal stress conditions, using binarization methods supplemented by scanning electron microscopy to explore the two-dimensional fracture damage characteristics of limestone joint surfaces. Based on the three-dimensional morphological characteristics of limestone joint surfaces, a method for automatically identifying the three-dimensional curvature of rock joint surfaces is proposed, quantifying the changes in curvature distribution under different normal stresses. Further analysis focused on the proportion of shear damage and high-curvature areas on the upper and lower joint surfaces of limestone. The study examined changes in the cumulative energy of pre-peak acoustic emission and damage under varying effective normal stress-to-shear stress ratios. These results were used to identify and validate the critical threshold range for inducing shear fractures in limestone. The conclusions indicate that the proportion of shear damage area of limestone joint surfaces is positively correlated with effective normal stress. The proportion of high curvature of limestone joint surfaces decreases with increasing normal stress. Both the rapid growth stage of shear damage area and the rapid descent stage of high curvature proportion occur in the effective normal stress to shear stress ratio range of [1.4, 1.6]. The cumulative energy of pre-peak acoustic emission and damage under different effective normal stress to shear stress ratios increase sharply around the ratio of 1.6, further verifying that the effective normal stress to shear stress ratio range of [1.4, 1.6] is the critical threshold range for inducing shear fractures in limestone.
Journal of Central South University•2025•DOI: 10.1007/s11771-025-6122-0
Composite rock layers are widely present in mining and tunnel construction projects, and are prone to dynamic tensile failure along bedding planes under dynamic disturbances. To ensure engineering safety, it is necessary to conduct research on the dynamic tensile characteristics under different working conditions. Considering the difficulty of on-site sampling, composite rock samples were prepared with cement mortar, and dynamic Brazilian splitting tests were carried out using split Hopkinson pressure bar (SHPB) equipment, a high-speed camera, and PFC2D numerical software to explore their dynamic tensile properties under dynamic disturbance under different strength ratios and other factors. The results show that the dynamic tensile strength of samples exhibits a rising trend with the strength ratio and strain rate growth. As the incident angle increases from 0° to 90°, the stress contour deflects transform from center-splitting failure to tension-shear combined failure and back again. The influence of the incident order in different lithology rocks on the dynamic tensile strength of composite samples is controlled by strain rate, and when the strain rate increases to 400 s−1, the difference in strength due to the sequence of incident stress waves is within 5%. Based on PFC2D, the strength ratio of composite samples has a certain influence on the distribution of microfractures. With strength ratios equaling 1.5 or 2.0, the cracks are mainly concentrated on the softer material side, while a large number of cracks are distributed on both sides of the bedding plane with a strength ratio equal to 1.2.
Int. Journal of Minerals, Metallurgy and Materials (矿物冶金与材料学报)•2025•DOI: 10.1007/s12613-025-3230-7
The effect of heavy metals on the properties and hydration of blast furnace slag–cement composites (BFS-CC) remain unclear. In this study, two BFS-CC (denoted as DBFS-CC and WBFS-CC) were prepared by dry and wet grinding of BFS, respectively. The effect of Cu(II) on BFS-CC’s properties and hydration was investigated by adding representative copper contaminants (CuO, CuCl2, and CuS) to the composites. Adding 1.0wt% CuO and 0.5wt% CuS increased the 3-d compressive strength of DBFS-CC by 14.9% and 5.7%, respectively, but suppressed the 3-d strength of WBFS-CC. This trend reversed at 28-d curing, where adding 1.5wt% CuO, 2.0wt% CuCl2, and 1.5wt% CuS enhanced the compressive strength of WBFS-CC by 23.4%, 6.2%, and 13.6%, respectively, but adversely affected the strength of DBFS-CC. For 28-d hydration, adding CuCl2 decreased the hydration degree of DBFS-CC but enhanced that of WBFS-CC. Adding CuO promoted the hydration degree of both composites, while adding CuS exhibited inhibitory effects. DBFS-CC immobilized CuCl2 better due to a higher hydration degree, while WBFS-CC immobilized CuO and CuS better due to having finer unhydrated BFS particles and a denser matrix. This study not only focuses on the Cu(II) immobilization effect but also reveals the differential effects of Cu(II) species on the hydration process, providing novel insights into heavy metal interactions in BFS-CC systems and their safe disposal.