Journal of Advanced Ceramics•2026•DOI: 10.26599/JAC.2026.9221348
Advanced temperature-sensitive materials are critical for hypersonic propulsion and next-generation energy systems, yet long-term stability above 1000 °C remains a formidable barrier. Conventional transition-metal spinel oxides (e.g., Ni–Mn–Co–O) suffer phase decomposition and cation migration above 300 °C, causing exponential resistance drift. This work develops a Mo-regulated high-entropy ferroelastic niobate strategy for ultrawide-temperature negative-temperature-coefficient (NTC) thermosensitive ceramics. Density functional theory calculations reveal that A-site high-entropy facilitates Mo doping in (Ca0.2La0.2Ce0.2Eu0.2Gd0.2)NbO4. Mo doping broadens local atomic configurations, modulates ferroelastic domain structures, and increases atomic-scale displacement disorder, redistributing Hall transport contributions and reducing grain/grain-boundary transport barrier mismatch. The optimized HEN-0.2Mo ceramic exhibits highly linear Arrhenius behavior (R² = 0.99907) from −50 to 1250 °C with a B-value fluctuation of only 4.44%. High-temperature impedance analysis confirms closely matched grain and grain-boundary activation energies (Eg = 1.209 eV, Egb = 1.218 eV; ΔEa ≈ 0.009 eV). During 1250 °C aging, postdensification and strain redistribution yield a stabilized-stage resistance drift of only 1.09% after 1000 h. These findings demonstrate that entropy-stabilized defect engineering decouples sensitivity from degradation in functional ceramics under thermal stress.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2026•DOI: 10.1016/j.ijmst.2026.02.006
The development of efficient CO2 adsorbents is critical for achieving net-zero targets. MgO represents a promising solid adsorbent for CO2 capture, yet its limited specific surface area and insufficient active sites restrict its adsorption capacity under moderate temperature conditions. A rod-like anhydrous MgCO3 precursor was hydrothermally synthesized and calcined at 500 °C for 3 h to obtain porous MgO (184.9 m2 g−1, 0.38 cm3/g), which was then modified with 20% NaNO2 (by mole) via impregnation. This adsorbent achieved an adsorption capacity of 12.6 mmol g−1 after 120 min under a pure CO2 atmosphere at 325 °C. Comprehensive characterization reveals that NaNO2 modification leads to the NaNO3 and Na2CO3 formation on the MgO surface during calcination. The introduced NaNO3 effectively promotes oxygen vacancy formation, while the generated Na2CO3 serves as heterogeneous nucleation sites, collectively reducing the reaction energy barrier and enhancing interfacial mass transfer. This synergistic effect facilitates the MgCO3 formation followed by its conversion to the thermodynamically more stable Na2Mg(CO3)2. Kinetic studies elucidate that adsorption is dominated by surface chemical reactions and diffusion mechanisms at different stages. These fundamental insights into the adsorption mechanisms of nitrite-modified MgO provide valuable guidance for the rational design of advanced MgO-based CO2 adsorbents with enhanced performance.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01759-4
Silicon suboxide (SiOx, 0<x<2) is an appealing anode material to replace traditional graphite owing to its much higher theoretical specific capacity enabling higher-energy-density lithium batteries. Nevertheless, the huge volume change and rapid capacity decay of SiOx electrodes during cycling pose huge challenges to their large-scale practical applications. To eliminate this bottleneck, a dragonfly wing microstructure-inspired polymer electrolyte (denoted as PPM-PE) is developed based on in-situ polymerization of bicyclic phosphate ester- and urethane motif-containing monomer and methyl methacrylate in traditional liquid electrolyte. PPM-PE delivers excellent mechanical properties, highly correlated with the formation of a micro-phase separation structure similar with dragonfly wings. By virtue of superior mechanical properties and the in-situ solidified preparation method, PPM-PE can form a 3D polymer network buffer against stress within the electrode particles gap, enabling much suppressed electrode volume expansion and more stabilized solid electrolyte interface along with evidently decreased electrolyte decomposition. Resultantly, PPM-PE shows significant improvements in both cycling and rate performance in button and soft package batteries with SiOx-based electrodes, compared with the liquid electrolyte counterpart. Such a dragonfly wing microstructure-inspired design philosophy of in-situ solidified polymer electrolytes helps facilitate the practical implementation of high-energy lithium batteries with SiOx-based anodes.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.07.005
Percussion drilling is a promising approach for hot dry rock (HDR) fragmentation. However, understanding of HDR fragmentation mechanism under multi-dimensional percussion remains limited and hinders the corresponding drilling performance. Herein, an innovative true triaxial multi-dimensional percussion device was developed for the study of HDR fragmentation mechanism under in-situ temperature and stress conditions. Multi-dimensional percussion, involving both axial and torsional components, was applied to drilling in granite and carbonatite rocks sampled from the typical HDR target areas. Multi-scale visualization techniques and a whale optimization-variational mode decomposition algorithm were employed to investigate the rock failure patterns and drilling energy characteristics. Results indicated that multi-dimensional percussion enhances brittle-ductile mixed failure in granite, characterized by transgranular, intergranular, and combined fracture patterns that promote rock cracking. In contrast, carbonatite drillhole displays enhanced brittle fragmentation and tortuous failure surface dominated by transgranular fracture pattern. Frequency-domain characteristics of penetration force signals for multi-dimensional percussion, especially the significant dominant frequency, amplitude, and high-frequency dissipation, indicate an increase in net energy for drilling into HDR and intensified rock fragmentation. Further, the effect of impact frequency on rock fragmentation performance was emphasized to maximize drilling efficiency. The optimal regulation schemes between axial and torsional impact frequencies are identified as 15 Hz + 15 Hz for granite and 30 Hz + 15 Hz for carbonatite. The reliability of the optimization approach was validated through a field test that employed a novel impactor in the geothermal well Fushen-1.
Chinese Journal of Mechanical Engineering•2025•DOI: 10.1186/s10033-025-01237-3
Electronic control suspension (ECS) systems are of significance to ride comfort and handling stability of ground vehicles. However, ECS systems may pose unreasonable safety risks due to performance inadequacies or improper use by drivers, which are referred to as safety of the intended functionality (SOTIF) issues. Aiming to address the inadequate performance of the ECS system, this study proposes a model predictive control (MPC) method, with a particular focus on ensuring SOTIF. First, Systems theoretic process analysis (STPA) is utilized to assess the SOTIF of the ECS system and the ECS system control architecture is built. Then, Models including the input model, lateral and vertical coupled dynamics model, and nonlinear actuator model are established. In addition, an MPC strategy with explicit dynamic constraints is designed, incorporating the dynamic mechanical performance boundaries of ECS actuators into the constraints of the controller. Subsequently, a hardware-in-the-loop testing platform is constructed for the ECS system to conduct simulation experiments under various operating conditions. Results demonstrate that the designed control strategy effectively mitigates performance inadequacies of the suspension system, significantly enhancing its overall functionality and safety.