• No liquid metal embrittlement was observed in any of the three 316L steels tested in LBE at 350 °C, regardless of processing method.
• LPBF 316L steel achieved the highest yield strength (420–435 MPa) owing to nanosized dislocation cell structures, but exhibited markedly lower ductility (~19%).
• PEP 316L steel had the lowest strength due to massive residual micropores, yet maintained ductility comparable to cast 316L (~40–43%).
• These findings support the potential use of additively manufactured 316L steels in LBE-cooled fast reactors, while highlighting the critical role of microstructural defects in mechanical performance.
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