• Microstructural parameters such as thickness, porosity, Zr/Ti ratio, doping, grain size, grain boundaries, and orientation critically influence the dielectric, ferroelectric, and piezoelectric properties of PZT ferroelectric films.
• Geometric structure (thickness and porosity) directly impacts electrical performance, with application-specific requirements dictating optimal dimensions and porosity.
• Compositional adjustments (Zr/Ti ratio and doping) alter phase composition, thereby tuning ferroelectric and piezoelectric responses.
• Grain structure (size, boundaries, orientation) affects domain dynamics and switching behavior, offering pathways for performance optimization in device design.
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