• A novel chiral (NEA)₂MnBr₄ was obtained by introducing three independently tunable primary-color emissive centers.
• Comparable emission intensities among the three primary colors were achieved by optimizing components and introducing chirality.
• By means of dual control of excitation photon energy and temperature, the sample can emit at least seven different colors, including standard white light emission at (0.33, 0.33).
• The material exhibits photoluminescence quantum yields up to 96% and shows promise for anti-counterfeiting, LEDs, X-ray imaging, latent fingerprint detection, and humidity sensing.
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