• Electroshock treatment (EST) induces phase transformation from acicular secondary αs to β phase in Ti−8Al−1Mo−1V alloy, with precipitation of acicular martensitic phase (αM) at 0.12 s.
• EST refines the average grain size from 3.95 μm to 2.53 μm, accompanied by significant recrystallization and martensitic transformation.
• EST leads to a more uniform texture distribution due to crystal orientation variations after phase transformation.
• EST significantly enhances yield strength while reducing fracture strain, primarily attributed to martensitic phase precipitation.
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