• Chemical blowing is a low-cost, facile, and highly controllable strategy to fabricate 3D graphene materials, effectively overcoming restacking.
• The strategy enables the construction of both macroscopic graphene foams and microscopic graphene powders with integrated macro/microstructural design.
• Synthesis chemistry determines the morphology and properties of the resulting graphene materials, allowing tailored functional applications.
• Future research should focus on addressing scalability challenges and exploring new blowing agents to expand the application landscape.
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