Transactions of Nonferrous Metals Society of China (中国有色金属学报)•2026•DOI: 10.1016/S1003-6326(26)67055-0
Ceramic matrix composites (CMCs) offer exceptional high-temperature performance and lightweight characteristics, yet their limited manufacturability restricts fabrication of complex, large-scale structural components. Ni-based superalloys exhibit outstanding elevated-temperature properties, and hybrid CMC/superalloy components can significantly expand engineering applications. Interfacial residual stresses arising from thermal expansion coefficient (CTE) mismatch, thermal gradient differences, and phase transformations severely impair joint performance. This review systematically examines residual stress formation mechanisms in CMCs/Ni-based superalloys joints and summarizes mitigation methodologies including interlayer techniques, composite filler approaches, and interface structure design strategies. Key experimental findings from recent studies demonstrate that composite fillers incorporating nanoparticles (e.g., Ag-CuO-Al2O3, Si3N4, Sc2W3O12, graphene nanosheets, carbon nanotubes, WC) effectively regulate interfacial reactions and relieve residual stresses. For instance, Ag-Cu-Ti+Sc2(WO4)3 composite filler reduced residual stress in Cf/SiC-GH3536 joints, while graphene nanoplatelets reinforced AgCuTi fillers improved SiC/GH99 joint integrity. Mo and B inserts in SiCf/SiC-Ni-based superalloy joints provided microstructural control and reinforcement. These methodologies address the critical bottleneck of CTE mismatch-induced stress concentration, offering pathways to reliable CMC/superalloy hybrid structures for aerospace, energy, and propulsion applications. Challenges remain in scaling these techniques for industrial production and ensuring long-term stability under service conditions.
Nano-Micro Letters•2026•DOI: 10.1007/s40820-025-01981-0
As an emerging thermal management strategy, dynamic radiative cooling (DRC) technology enables dynamic modulation of spectral radiation properties under varying environmental conditions through the directional design of material spectral characteristics. However, a comprehensive review of the basic physical mechanisms of radiative heat transfer in DRC materials and various design principles involved in dynamic radiative thermal regulation is still lacking. This review systematically summarizes recent advances in this field, spanning from fundamental physical principles to intrinsic molecular and electronic mechanisms, and further to representative material systems and multi-band regulation strategies, highlighting the interdisciplinary research achievements and technological innovations. This work outlines the core mechanisms governing the regulation of different spectral bands during radiative heat transfer processes. Then, the main categories of DRC materials are systematically reviewed, including actively responsive structures, passively responsive structures, and multi-stimuli-responsive materials. Furthermore, the challenges faced by current DRC technology and future development trends are summarized and discussed, providing valuable reference and guidance for further research in this field. Although DRC technologies still face significant challenges in material stability, manufacturing processes, and system integration, the continuous advances in related areas and multifunctional materials are expected to broaden the application prospects of DRC in the future.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-025-01951-6
Perovskite solar cells have achieved remarkable progress in photovoltaic efficiency. However, interfacial defects at the buried and upper interfaces of perovskite layer remain a critical challenge, leading to charge recombination, ion migration, and iodine oxidation. To address this, we propose a novel all-in-one modification strategy employing ammonia borane (BNH6) as a multifunctional complex. By incorporating BNH6 at both buried and upper interfaces simultaneously, we achieve dual-interfacial defect passivation and iodide oxidation suppression through three key mechanisms: (1) hydrolysis-induced interaction with SnO2, (2) coordination with Pb2+, and (3) inhibition of I− oxidation. This approach significantly enhances device performance, yielding a champion power conversion efficiency (PCE) of 26.43% (certified 25.98%). Furthermore, the unencapsulated device demonstrates prominent enhanced operation stability, maintaining 90% of its initial PCE after 500 h under continuous illumination. Notably, our strategy eliminates the need for separate interface treatments, streamlining fabrication and offering a scalable route toward high-performance perovskite photovoltaics.
International Journal of Mining Science and Technology•2026•DOI: 10.1016/j.ijmst.2025.10.004
Early prevention and control of coal spontaneous combustion have emerged as a critical research area in coal mine safety. Due to their sustainability and environmental friendliness, microorganisms have gained attention. A filamentous fungus was collected in the coal mine and identified as Absidia spinosa. Results indicated that the mycelium effectively covered and repaired many coal pores. The oxygen consumption ratio of A. spinosa was higher in coal-containing environments than in coal-free conditions. The fungus significantly impacted aliphatic functional groups, disrupting bridging bonds and side chains connected to aromatic structures and reducing the relative content of CAO bonds. Additionally, A. spinosa increases the ignition temperature by 25.34 °C. The total heat release was decreased by approximately 32.58 %, and the activation energies were increased. The genome of Absidia spinosa revealed genes related to oxygen consumption, small molecule degradation, and secretion of metabolic products, such as those annotated under GO ID: 0140657, etc. The pathways involved in the degradation of small organic molecules (e.g., ko00626, etc.), carbon fixation, and nitrogen cycling, all linked to coal decomposition. Through oxygen consumption and the alteration of coal-active structures, A. spinosa effectively inhibits CSC, providing an experimental basis for exploring eco-friendly biological control methods in the goaf.
Nano-Micro Letters•2025•DOI: 10.1007/s40820-024-01630-y
Finding ways to produce dense and smooth perovskite films with negligible defects is vital for achieving high-efficiency perovskite solar cells (PSCs). Herein, we aim to enhance the quality of the perovskite films through the utilization of a multifunctional additive in the perovskite anti-solvent, a strategy referred to as anti-solvent additive engineering. Specifically, we introduce ortho-substituted-4′-(4,4″-di-tert-butyl-1,1′:3′,1″-terphenyl)-graphdiyne (o-TB-GDY) as an AAE additive, characterized by its sp/sp2-cohybridized and highly π-conjugated structure, into the anti-solvent. o-TB-GDY not only significantly passivates undercoordinated lead defects (through potent coordination originating from specific high π–electron conjugation), but also serves as nucleation seeds to effectively enhance the nucleation and growth of perovskite crystals. This markedly reduces defects and non-radiative recombination, thereby increasing the power conversion efficiency (PCE) to 25.62% (certified as 25.01%). Meanwhile, the PSCs exhibit largely enhanced stability, maintaining 92.6% of their initial PCEs after 500 h continuous 1-sun illumination at ~23 °C in a nitrogen-filled glove box.
New Carbon Materials (新型炭材料)•2025•DOI: 10.1016/S1872-5805(NCM2024-39-05-09)
Zinc-ion capacitors (ZICs), which consist of a capacitor-type electrode and a battery-type electrode, not only possess the high power density of supercapacitors and the high energy density of batteries, but also have other advantages such as abundant resources, high safety and environmental friendliness. However, they still face problems such as insufficient specific capacitance, a short cycling life, and narrow operating voltage and temperature ranges, which are hindering their practical use. We provide a comprehensive overview of the fundamental theory of carbon-based ZICs and summarize recent research progress from three perspectives: the carbon cathode, electrolyte and zinc anode. The influence of the structure and surface chemical properties of the carbon materials on the capacitive performance of ZICs is considered together with theoretical guidance for advancing their development and practical use.
Int. Journal of Mining Science and Technology (采矿与安全工程)•2025•DOI: 10.1016/j.ijmst.2025.08.011
To study the relationships between rock mass crack propagation and damage and confining pressure under blast impact loading during straight-hole cut blasting, tests were performed under different confining pressures. Then, the characteristics of rock mass crack development were analyzed, and the pressure resistance values of core samples before and after blasting were compared to study the trends of rock mass damage. Moreover, a three-dimensional numerical simulation model was established by LS-DYNA to analyze the stress wave propagation, cavity shape and crack propagation characteristics under different confining pressures. The propagation of rock blasting cracks is negatively correlated with the confining pressure. The greater the confining pressure, the shorter the crack development time. Additionally, the crack width is reduced from 0.4–1.7 to 0.04–1.4 mm, and the length is shortened from 280 to 120 mm. A comparison of the compressive strength revealed that blasting reduces the compressive strength of the rock mass. The greater the distance from the explosion source, the lower the degree of strength attenuation. An increase in the confining pressure can inhibit strength attenuation. Numerical simulations revealed that under the same confining pressure, the stress first peaks at the bottom of the blast hole. The greater the confining pressure, the longer the stress peak duration, the smaller the cavity volume, and the shorter the crack propagation length and depth. Under a confining pressure of 4 MPa, the longest crack was only 154.5 mm in length and 102 mm in depth. The research results provide a scientific basis for controlling rock damage and optimizing design in the excavation of deep rock roadways by blasting.
China Foundry•2025•DOI: 10.1007/s41230-025-4265-0
Surface recrystallization (RX) is a typical grain defect observed in directionally solidified (DS) Ni-based superalloys. Most studies have focused on the RX behavior and its impact on the mechanical properties of single-crystal (SC) superalloys, with limited research on its influence on the high-temperature mechanical properties of DS superalloys. This study systematically investigated the effect of RX on the high-temperature tensile properties of a DS DZ409 superalloy. The results show that at 650 °C, the yield strength decreases almost linearly with an increase in RX fraction. A significant reduction in elongation is observed as the RX fraction increases from 0% to 4.9%. However, beyond this point, further increase in RX fraction leads to minimal changes in elongation. At 950 °C, both yield strength and elongation decrease as the RX fraction increases from 0% to 4.9%. At 650 °C, fractures in the RX DS superalloys exhibit a mixed mode of transgranular and intergranular cleavage fracture, while at 950 °C, it features a combination of ductile and intergranular dimple fractures. The failure mechanism of the RX DS superalloy is associated with the introduction of transverse grain boundaries (GBs) during RX. In the early stages of tensile testing at intermediate and high temperatures, cracks can easily initiate at these GBs. Subsequently, the cracks propagate along the GBs into the DS matrix, ultimately leading to failure of the DS superalloy.