• Heavy oil composition critically influences the structure and potassium storage performance of derived carbon nanosheets.
• FCCS-derived carbon nanosheets exhibit optimal properties: smaller layer thickness, larger interlayer spacing (0.372 nm), and more folds.
• CNS-FCCS delivers high capacity (248.7 mAh g−1 at 0.1 A g−1) and excellent cycling stability (190.8 mAh g−1 after 800 cycles at 1.0 A g−1).
• The molten salt method effectively converts heavy oils into high-performance carbon anodes for potassium-ion batteries.
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