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Synergistic enhancement of strength−ductility in Sn1.0Ag0.5Cu composite solder via surface-modified nano-sized ZrO2 and micro-sized T-ZnOw hybrid reinforcements

Authors: Fu-peng HUO; Chuan-tong CHEN; Zhi JIN; Xun-da LIU; Ke-ke ZHANG; Hiroshi NISHIKAWA

DOI: 10.1016/S1003-6326(25)67026-9Status: Verified Translated Edition
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Key Findings in This Report

• A novel SnAgCu composite solder with hybrid nano-ZrO2 and micro-T-ZnOw reinforcements was successfully fabricated via ultrasonic-assisted casting. • Surface modification of reinforcements using pyrolysis method ensured a clean interface with no gaps or new phases, promoting atomic inter-diffusion. • The composite solder exhibited a high proportion of eutectic structures and minimal coarse IMCs, enhancing mechanical properties. • Optimal Zn/Zr molar ratio of 2:3 yielded a 30.5% increase in ultimate tensile strength and 47.4% increase in elongation compared to plain Sn1.0Ag0.5Cu solder.
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