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Regulating the Coordination Environment of H2O in Hydrogel Electrolyte for a High-Environment-Adaptable and High-Stability Flexible Zn Devices

Authors: Jianghe Liu; Qianxi Dang; Jodie Yuwono; Shilin Zhang; Zhixin Tai; Zaiping Guo; Yajie Liu

DOI: 10.1007/s40820-025-01810-4Status: Verified Translated Edition
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Key Findings in This Report

• A hydrogel electrolyte regulation strategy of the water coordination environment can effectively restrain the hydrogen evolution reaction, Zn corrosion and dendrite formation in the wide-temperature ranges. • Prepared high-environment-adaptable hydrogel electrolytes (HEA-3) exhibits a high reversibility of zinc deposition/stripping (coulombic efficiency of 99.4% for Zn||Cu cell). • Zn-based device using HEA-3 electrolyte can do cycling over 30,000 cycles at a large current density of 2 A g−1 at −40 °C and also can do normal cycling even at -70 °C. • The manipulation of water coordination chemistry enables advanced, highly adaptable batteries for wide-temperature applications.