• Y2O3 doping up to 0.3 wt.% transforms the Fe45 coating microstructure from columnar to fine cellular/equiaxed grains, enhancing hardness by 14.06% and reducing wear volume by 51.16%.
• Excessive Y2O3 (0.9 wt.%) leads to coarser feather-like structures, degrading hardness and wear resistance, yet still outperforming undoped coatings.
• Rare-earth oxide modification offers a cost-effective alternative to process optimization for improving laser-clad Fe-based coatings.
• The study provides quantitative evidence for optimal Y2O3 content, guiding industrial application for wear-resistant coatings on carbon steel components.
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