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Joule Heating-Driven sp2-C Domains Modulation in Biomass Carbon for High-Performance Bifunctional Oxygen Electrocatalysis

Authors: Jiawei He; Yuying Zhao; Yang Li; Qixin Yuan; Yuhan Wu; Kui Wang; Kang Sun; Jingjie Wu; Jianchun Jiang; Baohua Zhang; Liang Wang; Mengmeng Fan

DOI: 10.1007/s40820-025-01725-0Status: Verified Translated Edition
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Key Findings in This Report

• Flash Joule heating controllably enhances sp2-C domains in N-doped biomass carbon, improving edge defects and graphitization. • The axial modulation of sp2-C domains tunes the electronic structure of pyridinic and graphitic N, boosting oxygen electrocatalysis. • Optimized catalyst achieves outstanding Zn-air battery performance: over 1200-h cycle stability and 121 mW cm−2 peak power density. • DFT simulations reveal the mechanism: sp2-C domains regulate local charge density, enhancing catalytic activity.
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