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Open AccessDOI: 10.1016/S1872-5805(NCM2026-41-02-01)Original Research

Functionalized carbon dots from natural precursors for environmental remediation and renewable energy technologies

Habtamu F Etefa¹,Francis B. Dejene¹

Department of Physics, Walter Sisulu University, Mthatha 5117, Eastern Cape, South Africa

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Academic Research Journal
Published:January 15, 2025Edition:Vol 40, Issue 1 • pp. 100-112Citation:Habtamu F Etefa et al. (2025), Academic Research Journal
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Key Takeaways & Executive Findings

  • • Green synthesis of carbon dots from biomass offers a sustainable route for nanomaterial production, addressing waste valorization and environmental footprint. • Functionalized carbon dots serve as efficient photocatalysts for degradation of organic pollutants and CO2 reduction, contributing to environmental remediation. • In renewable energy, carbon dots enhance light-harvesting in solar cells and dye-sensitized solar cells, improving energy conversion efficiency. • Challenges remain in controlling size, uniformity, and quantum yield scalability, necessitating further research on structure-activity relationships for commercial deployment.
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Abstract

The green synthesis of functionalized carbon dots (C-dots) from natural precursors is reviewed, providing a sustainable and versatile platform for environmental remediation and renewable energy technologies. The focus is on methods such as hydrothermal, microwave-assisted, pyrolytic, solvent-based, and ultrasonic routes, with an emphasis on biomass-derived precursors and green solvents. Strategies are given for surface passivation, hybridization, and composite formation to tailor their optical properties and their applications in sustainable technologies are examined. In environmental remediation, they act as efficient photocatalysts for degrading organic pollutants and reducing carbon dioxide (CO2). For renewable energy, they improve light-harvesting in solar cells and dye-sensitized solar cells. Their notable stability and efficiency are highlighted, alongside persistent challenges in controlling their size, uniformity, and scalability of quantum yield. Future work must clarify the structure-activity relationships for multifunctional compounds, facilitating commercial deployment.

1. Introduction

Global environmental crises, including pollution, greenhouse gas accumulation, and the pressing need for clean energy, have catalyzed the search for sustainable and high-performance nanomaterials. In this context, carbon dots (C-dots) have risen as a prime candidate, distinguished by their excellent photoluminescence, high aqueous solubility, tunable electronic properties, and facility surface functionalization. The synthesis of C-dots from biomass such as agricultural waste, lignocellulosic residues, and other natural precursors embodies green chemistry principles, transforming abundant, low-value resources into functional nanostructures with a minimal environmental footprint. This approach not only addresses waste valorization but also offers a sustainable pathway for nanomaterial production, as highlighted in recent reviews on circular economy-driven synthesis.

Functionalization of biomass-derived C-dots opens a gateway to modify their characteristics and develop target-specific applications, which is important. This contribution highlights the latest developments in green synthesis and modification of C-dots with a particular focus on their environmental applications regarding the mechanism of action and efficiency for environmental cleaning by means of photocatalytic dye degradation and heavy-metal sensing. Furthermore, it delves into their burgeoning potential in the renewable energy sector, including applications in hydrogen evolution reaction (HER), CO2 reduction, and as components in supercapacitors and dye-sensitized solar cells (DSSCs). By critically assessing current synthesis bottlenecks, performance limitations, and scalability challenges, this work aims to provide a forward-looking perspective on bridging laboratory-scale innovation with industrial-scale application.

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Cite This Research Paper
Habtamu F Etefa, Francis B. Dejene (2025). Functionalized carbon dots from natural precursors for environmental remediation and renewable energy technologies. SinoTechIntel Verified Research. https://doi.org/10.1016/S1872-5805(NCM2026-41-02-01)
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Frequently Asked Questions

What are carbon dots and why are they important?

Carbon dots are fluorescent carbon nanoparticles with excellent photoluminescence, high aqueous solubility, and tunable electronic properties. They are important for sustainable technologies due to their low toxicity, biocompatibility, and versatile surface functionalization, making them suitable for environmental remediation and renewable energy applications.

How are carbon dots synthesized from natural precursors?

Carbon dots are synthesized from natural precursors like fruit peels, agricultural waste, and lignocellulosic residues using green methods such as hydrothermal carbonization, microwave-assisted synthesis, pyrolysis, and ultrasonic treatment. These methods are solvent-efficient, low-energy, and scalable, embodying green chemistry principles.

What are the applications of carbon dots in environmental remediation?

Carbon dots act as efficient photocatalysts for degrading organic pollutants and reducing carbon dioxide (CO2). They also serve as sensors for heavy metals, contributing to environmental cleaning and monitoring.

How do carbon dots contribute to renewable energy technologies?

Carbon dots improve light-harvesting in solar cells and dye-sensitized solar cells, enhancing energy conversion efficiency. They are also used in hydrogen evolution reactions and supercapacitors, offering sustainable solutions for energy conversion and storage.

What are the main challenges in the field of carbon dots?

Key challenges include controlling the size, uniformity, and scalability of quantum yield. There is also a need to clarify structure-activity relationships for multifunctional compounds to facilitate commercial deployment.

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