• Carbon-sol-reinforced Cu composite coatings were successfully fabricated via electrodeposition, achieving uniform dispersion of carbon particles and enhanced coating quality.
• The optimal addition of 20 mL/L carbon sol significantly improved coating thickness, density, and uniformity, leading to superior wear and corrosion resistance.
• The Cu-CS composite coating exhibited a low wear volume (1.15 × 10−3 mm3), high hardness (HV0.5 137.1), and low corrosion rate (0.191 mm/a), attributed to strengthening and lubricating effects of carbon particles.
• Excessive carbon sol content compromises the microstructure, creating defects that undermine coating performance, highlighting the importance of optimizing reinforcement concentration.
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