• A novel Fe3O4/resin nanocomposite (FEOR) achieved an outstanding reflection loss of −71.09 dB at a thickness of only 1 mm.
• The FEOR sample exhibited near-ideal impedance matching (close to 1), leading to high absorption performance.
• The use of biomaterials (oleaster seeds and apricot tree gum) provides a sustainable approach to developing high-efficiency microwave absorbers.
• The presence of defects and porous structures enhances microwave attenuation through dipole polarization and charge carrier trapping.
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