• Solid-state electrolyte reactors enable direct synthesis of high-purity fuels and chemicals without traditional purification steps.
• The perspective systematically summarizes core components, variable configurations, and distinct electrochemical reaction mechanisms of different chambers.
• Applications span sustainable organic acid synthesis, H2O2 and ethanol production, ammonia synthesis, carbon capture, lithium recovery, and tandem strategies.
• Future prospects include advanced cell stack designs and industrial-scale deployment for environmental remediation and clean energy conversion.
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