• Green synthesis of CoFe2O4 nanoparticles using apple extract yields a mixed spinel phase with high surface area (347.04 m2/g) and mesoporosity.
• The nanoparticles exhibit 96.88% photo-Fenton degradation of Methylene Blue under visible light and 100% adsorption of Cr3+ and Pb2+ ions.
• Mössbauer spectroscopy confirms the presence of only Fe3+ ions in a Zeeman sextet pattern, indicating magnetic ordering.
• Statistical analysis (ANOVA and Tukey's HSD) validates that contact time and adsorbent dosage significantly influence pollutant removal efficiency.
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